147611-06-1Relevant articles and documents
Regioselective synthesis of 1-substituted 6-methoxy-3,3,4,4-tetramethyl-3,4-dihydroisoquinolines via Ritter reaction
Shklyaev,Rozhkova,Perevoshchikova,Gorbunov
, p. 2087 - 2091 (2014)
2-(4-Methoxyphenyl)-3,3-dimethylbutan-2-ol and nitriles undergo the Ritter reaction in concentrated sulfuric acid to give 1-R-6-methoxy-3,3,4,4-tetramethyl-3,4-dihydroisoquinolines.
Substituent effect on the solvolysis of α-t-butyl-α-methylbenzyl chlorides
Fujio, Mizue,Nomura, Hideyuki,Nakata, Kazuhide,Saeki, Yoshihiro,Mishima, Masaaki,Kobayashi, Shinjiro,Matsushita, Toshio,Nishomoto, Kichisuke,Tsuno, Yuho
, p. 5005 - 5008 (2007/10/02)
The substituent effect on the solvolysis rates of α-t-butyl-α- methylbenzyl chlorides in 80% aq. acetone was correlated to give p=-4.3 and r=0.91 in terms of the LArSR Eq. (1). This slightly reduced r value relative to full conjugation corresponds to a deviation by 0=24.5° from the coplanarity of the benzylic π-system.