1476744-48-5Relevant academic research and scientific papers
A cascade cross-coupling hydrogen evolution reaction by visible light catalysis
Meng, Qing-Yuan,Zhong, Jian-Ji,Liu, Qiang,Gao, Xue-Wang,Zhang, Hui-Hui,Lei, Tao,Li, Zhi-Jun,Feng, Ke,Chen, Bin,Tung, Chen-Ho,Wu, Li-Zhu
, p. 19052 - 19055 (2013)
Cross-dehydrogenative-coupling reaction has long been recognized as a powerful tool to form a C-C bond directly from two different C-H bonds. Most current processes are performed by making use of stoichiometric amounts of oxidizing agents. We describe her
Moderate oxidation levels of Ru nanoparticles enhance molecular oxygen activation for cross-dehydrogenative-coupling reactions: Via single electron transfer
Lin, Mu,Dai, Lin-Xiu,Gu, Jun,Kang, Li-Qun,Wang, Yu-Hao,Si, Rui,Zhao, Ze-Qiong,Liu, Wen-Chi,Fu, Xuefeng,Sun, Ling-Dong,Zhang, Ya-Wen,Yan, Chun-Hua
, p. 33078 - 33085 (2017/07/12)
For converting a homogeneous synthetic chemistry reaction to a heterogeneous one, using nanocatalysts, it is essential to investigate the underlying principles and the associated dominant factors of methodologies between inorganic nanoparticles and organi
A visible light-catalyzed cross-coupling preparing hydrogen product and method of coupling
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Paragraph 0097; 0098; 0117; 0118, (2017/01/09)
The invention discloses a method using visible light catalyzed cross-coupling reaction to prepare a coupling product and release hydrogen. The method is as follows: a tertiary amine, a nucleophile, a cobalt complexe 1 or a cobalt complexe 2 and eosin Y ar
Cobalt-catalyzed cross-dehydrogenative coupling reaction in water by visible light
Wu, Cheng-Juan,Zhong, Jian-Ji,Meng, Qing-Yuan,Lei, Tao,Gao, Xue-Wang,Tung, Chen-Ho,Wu, Li-Zhu
supporting information, p. 884 - 887 (2015/03/18)
By using catalytic amount of CoCl2 with dmgH (dimethylglyoxime) as ligand to form a photosensitizer in situ, a highly selective, efficient, and environmentally benign visible light mediated cross-dehydrogenative coupling (CDC) reaction has been
A Cascade Cross-Coupling and in Situ Hydrogenation Reaction by Visible Light Catalysis
Zhong, Jian-Ji,Wu, Cheng-Juan,Meng, Qing-Yuan,Gao, Xue-Wang,Lei, Tao,Tung, Chen-Ho,Wu, Li-Zhu
, p. 2846 - 2852 (2016/02/19)
An elegant cascade cross-coupling and in situ hydrogenation reaction has been established by visible light catalysis. Combining cheap and earth-abundant eosin Y as a photosensitizer and the cobalt chloride complex, Co(dmgH)2Cl2 (dmgH=dimethylglyoximate), as a catalyst, the desired oxidative cross-coupling products and reductive hydrogenation products could be achieved in good to excellent yields without use of any external oxidants and reductants under visible light irradiation.
Cross-coupling hydrogen evolution reaction in homogeneous solution without noble metals
Zhong, Jian-Ji,Meng, Qing-Yuan,Liu, Bin,Li, Xu-Bing,Gao, Xue-Wang,Lei, Tao,Wu, Cheng-Juan,Li, Zhi-Jun,Tung, Chen-Ho,Wu, Li-Zhu
supporting information, p. 1988 - 1991 (2014/05/06)
A highly efficient noble-metal-free homogeneous system for a cross-coupling hydrogen evolution (CCHE) reaction is developed. With cheap, earth-abundant eosin Y and molecular catalyst Co(dmgH)2Cl2, good to excellent yields for coupling reactions with a variety of isoquinolines and indole substrates and H2 have been achieved without any sacrificial oxidants. Mechanistic insights provide rich information on the effective, clean, and economic CCHE reaction.
