1476810-99-7Relevant academic research and scientific papers
An efficient oxidative cross-coupling reaction between C-H and N-H Bonds; A transition-metal-free protocol at room temperature
Wu, Yinuo,Kwong, Fuk Yee,Li, Pengfei,Chan, Alberts. C.
, p. 2009 - 2013 (2013)
A transition-metal-free oxidative coupling of allylic C-H and heterocyclic/aromatic N-H bonds was performed under mild conditions. Promoted by 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), up to 99% yield could be achieved. Georg Thieme Verlag Stuttgart, New York.
Oxovanadium(V)-Catalyzed Direct Amination of Allyl Alcohols
Sakuramoto, Takashi,Hirao, Toshikazu,Tobisu, Mamoru,Moriuchi, Toshiyuki
, p. 1175 - 1178 (2019/01/25)
Direct amination of allyl alcohols is regarded as one of reliable methods to synthesize allyl amines in one step because water is only by-product. Oxovanadium(V) compound with triphenyl siloxide ligands was demonstrated to serve as an efficient catalyst in the direct amination of allyl alcohols. The catalytic direct amination reaction could be performed with both aromatic and aliphatic amines. This catalytic system induced selective direct amination in the case of the unsymmetrically substituted allyl alcohols. Furthermore, gram-scale direct amination reaction was successfully achieved.
