3412-44-0

Basic information

• Product Name: 1,3-Diphenylpropene
• Synonyms: 1,3-Diphenyl-1-propene;1,3-Diphenylpropene;[(E)-3-phenylprop-1-enyl]benzene
• CAS NO: 3412-44-0
• Molecular Formula: C₁₅H₁₄
• Molecular Weight: 194.27166
• Mol File: 3412-44-0.mol
• Article Data: 299

Chemical Properties

• Boiling Point: 304.3°Cat760mmHg
• Flash Point: 141.4°C
• Appearance: /
• Density: 1.016g/cm³
• CAS DataBase Reference: 1,3-Diphenylpropene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Diphenylpropene(3412-44-0)
• EPA Substance Registry System: 1,3-Diphenylpropene(3412-44-0)

Safety Data

• Hazardous Substances Data: 3412-44-0(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 21, p. 27, 1980 DOI: 10.1016/S0040-4039(00)93615-3The Journal of Organic Chemistry, 31, p. 396, 1966 DOI: 10.1021/jo01340a012

Upstream product

• 122-78-1 phenylacetaldehyde 
• 1138-48-3 cis-1,2-diphenylcyclopropane 
• 1083-30-3 dihydrochalcone 
• 2016-03-7 2,3-diphenylpropanal 
• 1138-47-2 trans-1,2-diphenylcyclopropane 
• 329-98-6 phenylmethylsulphonyl fluoride 
• 33417-25-3 Benzylbenzylidendiphenylphosphoran 
• 54098-14-5 Tribenzylbenzylidenphosphoran 
• 75619-30-6 Benzylidene-tris-(4-methoxy-phenyl)-λ⁵-phosphane 
• 100-52-7 benzaldehyde 
• 103-63-9 1-phenyl-2-bromoethane 
• 82294-45-9 Triphenyl-(2-phenyl-1-trimethylsilanyl-ethyl)-phosphonium; bromide 
• 193829-29-7 1,3-diphenylacetone dimethyl acetal 
• 105-58-8 Diethyl carbonate 

Downstream Products

• 5381-80-6 rac-(1R,2R)-1,3-diphenylpropane-1,2-diol 
• 56363-42-9 C₁₅H₁₄Br₂ 
• 116118-10-6 1,3-diphenyl-1,3-dimethoxy-2-phenylselenenyl propane 
• 116117-95-4 1,3-diphenyl-1-methoxy-2-phenylselenenyl propane 
• 116118-07-1 1,3-diphenyl-1-methoxy-2-chloro propane, erythro 
• 116118-08-2 1,3-diphenyl-1,2-dimethoxy propane, erythro 
• 116118-11-7 1,1,2-trimethoxy-2,3-diphenyl propane 
• 62753-15-5 3-nitro-1,3-diphenyl-1-propene 
• 34862-96-9 3-bromro-1,3-diphenyl-1-propene 
• 7349-06-6 (1E,3E)-penta-1,3-diene-1,5-diyldibenzene 
• 12312-69-5 trans,trans-Diphenyl allyl anion 
• 1138-83-6 C₁₅H₁₄⁽¹⁺⁾ 
• 65095-03-6 trans-1,2-epoxy-1,3-diphenylpropane 
• 61608-80-8 1,3-diphenylallyllithium 

Relevant articles and documents

Nickel-Catalyzed C-Br/C-H Bis-phenylation of Methyl 4-Bromocrotonate: A Stereoselective Entry to Methyl (E)-3,4-Diphenylbut-2-enoate

A method for C-Br/C-H bis-phenylation of methyl 4-bromocrotonate via nickel-catalyzed cross-coupling reaction has been developed. This protocol involves commercially available catalyst components and furnishes a suitable doubly phenylated building block.

Vinylation of Benzylic Amines via C-N Bond Functionalization of Benzylic Pyridinium Salts

Cross-couplings of benzylic pyridinium salts and vinylboronic acids or esters have been developed. Via benzylic pyridinium intermediates, benzylic amines can be engaged in these cross-couplings through C-N bond functionalization. This method boasts mild reaction conditions and excellent tolerance for heteroaryl substituents and a range of functional groups.

Palladacycle-Catalyzed Regioselective Heck Reaction Using Diaryliodonium Triflates and Aryl Iodides

We describe a P-containing palladacycle-catalyzed regioselective Heck reaction of 2,3-dihydrofuran with diaryliodonium salts and aryl iodides to afford 2-aryl-2,5-dihydrofurans and 2-aryl-2,3-dihydrofurans, respectively, in good yields. Mechanistic studie

Ru-Catalyzed Selective Catalytic Methylation and Methylenation Reaction Employing Methanol as the C1 Source

Methanol can be employed as a green and sustainable methylating agent to form C-C and C-N bonds via borrowing hydrogen (BH) methodology. Herein we explored the activity of the acridine-derived SNS-Ru pincer for the activation of methanol to apply it as a C1 building block in different reactions. Our catalytic system shows great success toward the β-C(sp3)-methylation reaction of 2-phenylethanols to provide good to excellent yields of the methylated products. We investigated the mechanistic details, kinetic progress, and temperature-dependent product distribution, which revealed the slow and steady generation of in situ formed aldehyde, is the key factor to get the higher yield of the β-methylated product. To establish the environmental benefit of this reaction, green chemistry metrics are calculated. Furthermore, dimerization of 2-naphthol via methylene linkage and formation of N-methylation of amine are also described in this study, which offers a wide range of substrate scope with a good to excellent yield.