147688-25-3Relevant academic research and scientific papers
Studies on development of sufficiently chemoselective N-acylation reagents: N-Acyl-N-(2,3,4,5,6-pentafluorophenyl)methanesulfonamides
Kondo, Kazuhiro,Sekimoto, Erika,Nakao, Junko,Murakami, Yasuoki
, p. 5843 - 5856 (2007/10/03)
A variety of storable N-acyl-N-(2,3,4,5,6-pentafluorophenyl)methanesulfonamides (4a-e) prepared from N-2,3,4,5,6-pentafluorophenylmethanesulfonamide (3), have been developed after systematic research on the structure-reactivity relationship and were found to serve as N-acylation reagents exhibiting sufficiently good chemoselectivity. (C) 2000 Elsevier Science Ltd.
Chemoselective alkoxycarbonylation reagent having trifluoromethylsulfonyl-4-trifluoromethylanilide as a leaving group
Yasuhara, Tomohisa,Nagaoka, Yasuo,Tomioka, Kiyoshi
, p. 2233 - 2234 (2007/10/03)
N-Benzyloxy- and N-tert-butoxycarbonyltrifluoromethylsulfonyl-4-trifluoromethylanilides were prepared and were found to be chemoselective and shelf-storable alkoxycarbonylation reagents.
N-Benzyloxycarbonylaziridine in the Syntheses of 2-Aminoethyl Armed Lariats and Selectively N-Protected Polyazacrown Ethers
Zinic, Mladen,Alihodzic, Sulejman,Skaric, Vinko
, p. 21 - 26 (2007/10/02)
The 15- and 18-membered mono- and bi-bracchial N-aminoethylene armed lariats 6, 7 and 8 have been synthesized by alkylations of parent azacrowns using N-benzyloxycarbonylaziridine 2 and subsequent removal of Z-protecting groups by catalytic hydrogenolysis
A NEW AMINO PROTECTING GROUP READILY REMOVABLE WITH NEAR ULTRAVIOLET LIGHT AS AN APPLICATION OF ELECTRON-TRANSFER PHOTOCHEMISTRY
Hamada, Tatsuo,Nishida, Atsushi,Yonemitsu, Osamu
, p. 4241 - 4244 (2007/10/02)
As an extension of organic photochemistry via intermolecular electron-transfer in donor-acceptor pair systems between electron-rich aromatic compounds and electron-deficient tosyl groups, we report here a new protecting group for the amino-function, 4-(4,8-dimethoxy-naphthylmethyl)benzenesulfonyl (DNMBS) group, which is readily removed, via an intramolecular electron-transfer followed by hydrolysis, with a high quantum efficiency on irradiation with light longer than 300 nm.
