148043-45-2Relevant academic research and scientific papers
A search for maximal neighboring group participation in Solvolyses of allylic substrates. Ethanolysis of 2-(ω-alkylthioalkyl)-3-methyl-2-cyclohexenyl p-nitrobenzoates
Jursic, Branko S.,Ladika, Mladen,Sunko, Dionis E.
, p. 2717 - 2728 (2007/10/02)
The solvolysis of 2-(ω-methylthioalkyl)- and 2-(ω-benzylthioalkyl)-3-methyl-2-cyclohexenyl p-nitrobenzoates 5 and 6 in 80 vol % ethanol includes several competitive reactions. Path k1 is a stepwise process (kH/kD = 1.18-1.
NEIGHBORING SULFUR PARTICIPATION IN THE SOLVOLYSIS OF 2-(ω-ALKYLTHIOALKYL)-3-METHYL-2-CYCLOHEXENYL p-NITROBENZOATES
Ladika, Mladen,Jursic, Branko,Mihalic, Zlatko,Sunko, Dionis E.
, p. 1703 - 1706 (2007/10/02)
As shown by kinetic and product analysis, the solvolysis of 7 and 8 in 97percent TFE includes several competitive reactions, one of them being neighboring sulfur participation and formation of intermediate cyclic sulfonium cation.
