1483-74-5

Usage

Uses

Used in Organic Synthesis:
1,1,4,4-Tetraphenyl-2-butyn-1,4-diol is used as a building block in organic synthesis for its ability to facilitate the creation of complex organic molecules. Its unique structure allows for versatile chemical reactions, making it a valuable component in the synthesis of a wide array of organic compounds.
Used in Materials Science:
In the field of materials science, 1,1,4,4-Tetraphenyl-2-butyn-1,4-diol is used as a precursor for the preparation of various materials. Its properties contribute to the development of new materials with specific characteristics, such as dyes, pigments, and other specialty chemicals.
Used in Pharmaceutical Industry:
1,1,4,4-Tetraphenyl-2-butyn-1,4-diol is used as a precursor in the pharmaceutical industry for the production of pharmaceuticals. Its role in the synthesis of drug molecules is crucial, given its ability to form the backbone or key functional groups in medicinal compounds.
Used in Dye and Pigment Production:
1,1,4,4-TETRAPHENYL-2-BUTYN-1,4-DIOL is utilized as a component in the production of dyes and pigments due to its chemical structure that can contribute to the color and stability of these products.
Used in Antioxidant-Based Products:
1,1,4,4-Tetraphenyl-2-butyn-1,4-diol is used as an antioxidant in the development of products that require protection against oxidation, such as in the food and cosmetics industries, where its antioxidant properties can help preserve the quality and extend the shelf life of products.

InChI:InChI=1/C28H22O2/c29-27(23-13-5-1-6-14-23,24-15-7-2-8-16-24)21-22-28(30,25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-20,29-30H

Upstream product

• 4301-15-9 ethynyldimagnesium dibromide 
• 119-61-9 benzophenone 
• 60-29-7 diethyl ether 
• 1066-26-8 sodium acetylide 
• 75-20-7 calcium carbide 
• 75-07-0 acetaldehyde 
• 3923-52-2 1,1-diphenyl-2-propyn-1-ol 
• 115-19-5 2-methyl-but-3-yn-2-ol 
• 74-86-2 acetylene 
• 111440-97-2 Phosphorsaeure-diethyl- 
• 3848-49-5 1,1-diphenyl-2-propyn-1-yl acetate 
• 762-42-5 dimethyl acetylenedicarboxylate 
• 623-47-2 propynoic acid ethyl ester 
• 100-58-3 phenylmagnesium bromide 

Downstream Products

• 10487-75-9 1,4-dimethoxy-1,1,4,4-tetraphenyl-but-2-yne 
• 854418-07-8 1,1,4,4-tetraphenyl-1,4-dipropoxy-but-2-yne 
• 858504-21-9 2-methyl-6,6,11-triphenyl-6,6a-dihydro-indeno[1,2-c]chromene 
• 25236-18-4 4-ethoxy-1,1,4,4-tetraphenyl-but-2-yn-1-ol 
• 89815-49-6 1,4-diethoxy-1,1,4,4-tetraphenyl-but-2-yne 
• 33929-52-1 1-benzhydrylidene-3-phenyl-indene 
• 1483-68-7 tetraphenylbutatriene 
• 1450-63-1 1,1,4,4-tetraphenyl-1,3-butadiene 
• 63469-15-8 1,1,4,4-tetraphenyl-1,4-butanediol 
• 411220-98-9 1-benzhydrylidene-2-chloro-3-phenyl-indene 
• 84072-33-3 cis-1,1,4,4-tetraphenyl-2-butene-1,4-diol 
• 59856-52-9 trans-1,1,4,4-tetraphenyl-2-butene-1,4-diol 
• 876477-49-5 3-iodo-2,2,5,5-tetraphenyl-2,5-dihydro-furan 
• 36992-21-9 3,4-dibromo-2,2,5,5-tetraphenyl-2,5-dihydrofurane 

Relevant academic research and scientific papers

Rhodium-Catalyzed Arylative Transformations of Propargylic Diols: Dual Role of the Rhodium Catalyst

Controllable synthesis of a variety of allenic alcohols and 2,5-dihydrofurans by rhodium(I)-catalyzed arylative transformations of propargylic diols is reported. The hydroxorhodium catalyst was found to play dual role: it catalyzed the arylation/dehydroxylation reaction of propargylic diols to afford allenic alcohols, and besides, it could convert to a cationic rhodium species in situ, which catalyzed the intramolecular hydroalkoxylation of allenic alcohols to form dihydrofurans. Remarkably, generation of the cationic rhodium species is dependent on the arylboron reagent used. Thus, the controllable synthesis is achieved by simply changing the arylboron reagent. (Figure presented.).

Direct Exploitation of the Ethynyl Moiety in Calcium Carbide Through Sealed Ball Milling

Ball milling of calcium carbide (CaC2) enables the reaction of its ethynyl moiety with organic electrophiles. This was realized simply by co-milling CaC2 with organic substrates in a sealed jar without the need for an additive or a catalyst. Various ketones including those bearing α-hydrogens were ethynylated in good yields at short reaction times. Aryl halides are also amenable substrates for this protocol as they furnish aryl ethynes through a benzyne intermediate. This method offers a practical and cheap alternative to the established procedures for introducing ethynyl functionalities.

Mechanosynthesis of Odd-Numbered Tetraaryl[n]cumulenes

A mechanochemical synthesis of one-dimensional carbon allotrope carbyne model compounds, namely tetraaryl[n]cumulenes (n=3, 5) was realized. Central for the mechanosynthesis of the cumulenic carbon nanostructures were the development of a mechanochemical Favorskii alkynylation-type reaction and the implementation of a solvent-free, acid-free reductive elimination with tin(II) chloride by ball milling.

Synthesis of Polycyclic Spironaphthofuran Derivatives by Acid-Catalyzed Domino Reaction of 2-Naphthols with Tetraarylbut-2-yne-1,4-diols

The acid-catalyzed condensation of 2-naphthols with tetraphenylbut-2-yne-1,4-diols affords a mixture of spiro[indene-1,1′-naphthofurans] and dinaphthofurans through a cascade of intramolecular reactions, whereas using the more reactive thienyltriphenylbut

Colour switching with photochromic vinylidene-naphthofurans

A series of novel photochromic vinylidene-naphthofurans with extended conjugation, and a free hydroxyl function, were easily prepared using the Suzuki reaction. After silanization, these dyes were embedded in ormosil matrices affording solid and transpare

A Four-Step Synthesis of Substituted 5,11-Dicyano-6,12-diaryltetracenes with Enhanced Stability and High Fluorescence Emission

A four-step synthesis of substituted 5,11-dicyano-6,12-diaryltetracenes was developed, starting from readily available para-substituted benzophenones. The key step of this straightforward route is the complex cascade reaction between tetraaryl[3]cumulenes

Acid-catalyzed domino reactions of tetraarylbut-2-yne-1,4-diols. Synthesis of conjugated indenes and inden-2-ones

The reaction of tetraarylbut-2-yne-1,4-diols with electron-rich aromatic compounds at room temperature, under p-TsOH catalysis, affords substituted polycyclic aromatic indene derivatives through a domino reaction involving the formation of a cationic allenylium intermediate. This species can undergo a series of competitive intramolecular cascade reactions, leading to a conjugated inden-2-one. This simple method allows the efficient synthesis of substituted indenes and inden-2-ones, in two steps, from aromatic ketones.

Synthesis of 1-vinylidene-naphthofurans: A Thermally reversible photochromic system that colors only when adsorbed on silica gel

A set of new 1-vinylidene-1,2-dihydro-naphtho[2,1-b]furans were unexpectedly obtained in the reaction of 2-naphthol with readily available 1,1,4,4-tetraarylbut-2-yne-1,4-diols. Surprisingly, when adsorbed in silica gel, these compounds exhibit photochromism at room temperature, whereas not in solution and in the solid state. UV or sunlight irradiation leads, in a few seconds, to the formation of intense pink/violet to green colors that bleach completely in a few minutes in the dark. These new compounds also exhibit reversible acidochromic properties in solution: addition of TFA leads to the opening of the furan ring and addition of a proton to the allene function, leading to a conjugated and violet tertiary carbocation that returned immediately to the uncolored allenic structure upon addition of a weak base.

SLIME REMOVER AND SLIME PREVENTING/REMOVING AGENT

A drainage slime remover capable of spreading a solution of a solid over slime generated wall surface portions, comprising a solid containing a microorganism growth retarding substance and a container which has a shape for permitting the installation thereof at the inlet or upper portion of a drain outlet and stores the solid characterized in that the container has drain flow-in holes having an opening capable of controlling a drain flow-in amount and provided in the upper surface or the upper side portion of the container and solution flow-out holes having an opening capable of controlling a flow-out amount of a solid solution and provided in the bottom or the lower side portion of the container or additionally in the side surface thereof, and a slime preventing/removing agent which can remove slime from portions such as kitchen sinks and bathroom drain outlets where slime is grown by metabolites such as miscellaneous germs and mildews and which can prevent the occurrence of slime safely and for an extended period of time.

Electron transfer and contact ion pair formation, 45 [1, 2] structural changes on single electron reduction of tetraphenylbutatriene to its radical anion and on twofold deprotonation of tetraphenylbutyne-2 to the tetraphenylbutatriene dianion

Tetraphenylbutatriene is reduced under aprotic conditions to its ESR/ENDOR-spectroscopically characterized radical anion and to its dianion, with both electron transfers quasi-reversible according to cyclovoltammetric measurements. The alkali cation salts