148345-18-0Relevant academic research and scientific papers
Synthesis of dihydronaphthalenes via aryne Diels-Alder reactions: Scope and diastereoselectivity
Dockendorff, Chris,Sahli, Stefan,Olsen, Madeline,Milhau, Ludovic,Lautens, Mark
, p. 15028 - 15029 (2007/10/03)
Novel aryne Diels-Alder reactions with functionalized acyclic dienes are reported. These give useful cis-substituted dihydronaphthalene building blocks in good yield which are not easily accessible via other means, as demonstrated in the synthesis of sert
RING-OPENING OF 4-ISOXAZOLINES: COMPETITIVE FORMATION OF ENAMINO DERIVATIVES AND α,β-ENONES
Chiacchio, Ugo,Casuscelli, Franco,Liguori, Angelo,Rescifina, Antonio,Romeo, Giovanni,et al.
, p. 585 - 600 (2007/10/02)
Ring-opening of 3-substituted 4-isoxazolines, proceeding through the intermediate isoxazolinium salts, follows two competing reaction pathways leading to α,β-enones and enamines respectively.The rearrangement courses can be controlled as a function of substitution pattern and experimental conditions.
