4364-05-0

Upstream product

• 5443-49-2 α-bromocinnamaldehyde 
• 16694-46-5 ethyl formimidate hydrochloride 
• 122-51-0 orthoformic acid triethyl ester 
• 33603-90-6 (2Z)-2-bromo-3-phenyl-2-propenal 
• 64-17-5 ethanol 
• 78-39-7 Triethyl orthoacetate 
• 104-55-2 3-phenyl-propenal 
• 14371-10-9 (E)-3-phenylpropenal 
• 99686-39-2 (E)-2-bromo-3-phenylprop-2-enal 

Downstream Products

• 475148-07-3 2,4-di[(E)-benzylidene]-1,1,5,5-tetraethoxy-3-pentanol 
• 869732-64-9 (Z)-2-Diethoxymethyl-3-phenyl-acrylic acid ethyl ester 
• 1379480-16-6 (Z)-S-3-oxo-1-phenylprop-1-en-2-yl diisopropylcarbamothioate 
• 1379479-99-8 S-(1S,2R,3R,4R)-2-formyl-3-phenylbicyclo[2.2.1]hept-5-en-2-yl diisopropylcarbamothioate 
• 184175-27-7 (E)-4-Diethoxymethyl-2-((E)-2-diethoxymethyl-3-phenyl-allyl)-5-phenyl-pent-4-enenitrile 
• 184175-23-3 4-Oxo-2,6-bis-[1-phenyl-meth-(E)-ylidene]-heptanedioic acid 
• 184175-28-8 4-Oxo-2,6-bis-[1-phenyl-meth-(E)-ylidene]-heptanedial 
• 184175-26-6 ((Z)-2-Bromomethyl-3,3-diethoxy-propenyl)-benzene 
• 184175-24-4 2,4-di[(E)-benzylidene]-3-hydroxypentanedioic acid 
• 184175-29-9 2,4-di[(E)-benzylidene]-3-hydroxypentanedial 
• 148345-18-0 (Z)-ethyl 2-formyl-3-phenyl-2-propeonate 
• 869732-38-7 (E)-4-[1-Phenyl-meth-(Z)-ylidene]-pent-2-enedioic acid 5-ethyl ester 1-methyl ester 
• 951024-86-5 (E)-2-Diethoxymethyl-3-phenyl-prop-2-en-1-ol 
• 951024-70-7 (E)-2-hydroxymethyl-3-phenyl-2-propenal 

Relevant academic research and scientific papers

Modular Synthesis of α-Substituted Alkenyl Acetals by a Palladium-Catalyzed Suzuki Reaction of α-Haloalkenyl Acetals with Organoboranes

A modular and straightforward synthetic strategy for the preparation of α-substituted alkenyl acetals has been developed. α-Haloalkenyl acetals react smoothly with (het)aryl boronic acids, aryl boronates, or B-Alkyl-9-borabicyclo[3.3.1]nonanes through Pd-catalyzed Suzuki cross-coupling under mild conditions with good to high yields. This protocol features a broad substrate scope and good functional-group compatibility, and is easily scaled up.

Enantioselective Diels-Alder reaction of α-(acylthio)acroleins: A new entry to sulfur-containing chiral quaternary carbons

A catalytic and enantioselective Diels-Alder reaction of α-(carbamoylthio)acroleins induced by an organoammonium salt of chiral triamine is described. α-(Carbamoylthio)acroleins are designed and synthesized as new sulfur-containing dienophiles for the fir

New entry to convertible isocyanides for the Ugi reaction and its application to the stereocontrolled formal total synthesis of the proteasome inhibitor omuralide

The development of a new convertible isocyanide, indole-isocyanide, for ready access to pyroglutamic acids culminated in the formal total synthesis of the proteasome inhibitor omuralide featuring a stereocontrolled Ugi reaction. Indole-isocyanide was name

Synthesis of dihydronaphthalenes via aryne Diels-Alder reactions: Scope and diastereoselectivity

Novel aryne Diels-Alder reactions with functionalized acyclic dienes are reported. These give useful cis-substituted dihydronaphthalene building blocks in good yield which are not easily accessible via other means, as demonstrated in the synthesis of sert