4364-05-0

Basic information

• Product Name: Benzene, (2-bromo-3,3-diethoxy-1-propen-1-yl)-
• CAS NO: 4364-05-0
• Molecular Formula: C13H17BrO2
• Molecular Weight: 285.181
• Mol File: 4364-05-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, (2-bromo-3,3-diethoxy-1-propen-1-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (2-bromo-3,3-diethoxy-1-propen-1-yl)-(4364-05-0)
• EPA Substance Registry System: Benzene, (2-bromo-3,3-diethoxy-1-propen-1-yl)-(4364-05-0)

Safety Data

• Hazardous Substances Data: 4364-05-0(Hazardous Substances Data)

Upstream product

• 99686-39-2 (E)-2-bromo-3-phenylprop-2-enal 
• 122-51-0 orthoformic acid triethyl ester 
• 33603-90-6 (2Z)-2-bromo-3-phenyl-2-propenal 
• 78-39-7 Triethyl orthoacetate 
• 14371-10-9 (E)-3-phenylpropenal 
• 64-17-5 ethanol 
• 5443-49-2 α-bromocinnamaldehyde 
• 16694-46-5 ethyl formimidate hydrochloride 
• 104-55-2 3-phenyl-propenal 

Downstream Products

• 869732-64-9 (Z)-2-Diethoxymethyl-3-phenyl-acrylic acid ethyl ester 
• 1379480-16-6 (Z)-S-3-oxo-1-phenylprop-1-en-2-yl diisopropylcarbamothioate 
• 1379479-99-8 S-(1S,2R,3R,4R)-2-formyl-3-phenylbicyclo[2.2.1]hept-5-en-2-yl diisopropylcarbamothioate 
• 2579-22-8 Phenylpropargyl aldehyde 
• 184175-27-7 (E)-4-Diethoxymethyl-2-((E)-2-diethoxymethyl-3-phenyl-allyl)-5-phenyl-pent-4-enenitrile 
• 184175-23-3 4-Oxo-2,6-bis-[1-phenyl-meth-(E)-ylidene]-heptanedioic acid 
• 184175-28-8 4-Oxo-2,6-bis-[1-phenyl-meth-(E)-ylidene]-heptanedial 
• 184175-26-6 ((Z)-2-Bromomethyl-3,3-diethoxy-propenyl)-benzene 
• 475148-07-3 2,4-di[(E)-benzylidene]-1,1,5,5-tetraethoxy-3-pentanol 
• 184175-24-4 2,4-di[(E)-benzylidene]-3-hydroxypentanedioic acid 
• 184175-29-9 2,4-di[(E)-benzylidene]-3-hydroxypentanedial 
• 148345-18-0 (Z)-ethyl 2-formyl-3-phenyl-2-propeonate 
• 869732-38-7 (E)-4-[1-Phenyl-meth-(Z)-ylidene]-pent-2-enedioic acid 5-ethyl ester 1-methyl ester 
• 951024-86-5 (E)-2-Diethoxymethyl-3-phenyl-prop-2-en-1-ol 

Relevant articles and documents

Modular Synthesis of α-Substituted Alkenyl Acetals by a Palladium-Catalyzed Suzuki Reaction of α-Haloalkenyl Acetals with Organoboranes

A modular and straightforward synthetic strategy for the preparation of α-substituted alkenyl acetals has been developed. α-Haloalkenyl acetals react smoothly with (het)aryl boronic acids, aryl boronates, or B-Alkyl-9-borabicyclo[3.3.1]nonanes through Pd-catalyzed Suzuki cross-coupling under mild conditions with good to high yields. This protocol features a broad substrate scope and good functional-group compatibility, and is easily scaled up.

New entry to convertible isocyanides for the Ugi reaction and its application to the stereocontrolled formal total synthesis of the proteasome inhibitor omuralide

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