14860-82-3 Usage
General Description
1-Chloro-4-propoxybutane is a chemical compound used in various scientific research and applications. Typically appearing as a clear liquid, it is identified by its single chlorine atom and propoxy (propyl ether) group. It has distinct properties, including being less dense than water and having a relatively high boiling point. As with many organic compounds, safety considerations must be taken into account as it may cause irritation if it comes into contact with the skin and eyes, or if ingested or inhaled. It plays significant roles in different chemical synthesis due to its reactive nature.
Check Digit Verification of cas no
The CAS Registry Mumber 14860-82-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,8,6 and 0 respectively; the second part has 2 digits, 8 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 14860-82:
(7*1)+(6*4)+(5*8)+(4*6)+(3*0)+(2*8)+(1*2)=113
113 % 10 = 3
So 14860-82-3 is a valid CAS Registry Number.
InChI:InChI=1/C7H15ClO/c1-2-6-9-7-4-3-5-8/h2-7H2,1H3
14860-82-3Relevant articles and documents
ON THE MECHANISM OF SELECTIVE CHLORINATION OF ETHERS WITH SULFURYL CHLORIDE IN THE DARK
Buyck, Laurent De,Pooter, Herman De
, p. 807 - 816 (2007/10/02)
Alkyl 4-chlorobutyl ethers reacted in the dark with an excess of sulfuryl chloride at 70-85 deg C (bath) to afford α,β,β-trichlorinated ethers.The reactions were accelerated 3- to 6-fold by N,N-dimethyloctylammonium salts (0,12 to 1 mmol/mol ether).This catalyst promoted decomposition of sulfuryl chloride to chlorine and sulfur dioxide and thereby caused serious loss of sulfuryl chloride.The proportions of chlorination at α or α1 position were identical in the catalyzed or uncatalyzed version and depended on inductive effects, correlating well with Taft's linear free energy relationship log k/kref=ρ*?* for R = H, Me, Et, Pr in RCH2O(CH2)4Cl with ρ* = -2.6 +/- 0.1.The overall reactivity of ethers appears to vary like the nucleophilicity of the ether oxygen.It is concluded that hydride abstraction occurs indirectly, probably involving a chloroxonium ion pair.
