148675-55-2

Upstream product

• 26903-66-2 2-isopropylallyl alcohol 
• 824-94-2 p-methoxybenzyl chloride 

Downstream Products

• 1027182-23-5 (S)-2-Hydroxy-4-(4-methoxy-benzyloxymethyl)-5-methyl-hex-4-enoic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester 
• 189366-70-9 4-(4-methoxyphenyl)-2-(2-propyl)butanal 
• 198693-91-3 2-Hydroxy-4-(4-methoxy-benzyloxymethyl)-5-methyl-hex-4-enoic acid cyclohexyl ester 
• 198693-94-6 2-Hydroxy-4-(4-methoxy-benzyloxymethyl)-5-methyl-hex-4-enoic acid 1,2-dimethyl-propyl ester 
• 203640-38-4 4-(4-ethoxyphenyl)-2-methylbutanal 
• 148675-60-9 ethyl (4S)-(2Z)-4-<(t-butyldimethylsilyl)oxy>-3-<(diethylphosphoryl)oxy>-6-<(4-methoxybenzyloxy)methyl>-7-methyl-2,6-octadienoate 
• 148763-52-4 ethyl 2-hydroxy-4-<(4-methoxybenzyloxy)methyl>-5-methyl-4-hexenoate 
• 148675-61-0 ethyl (4S)-(2Z)-4-<(t-butyldimethylsilyl)oxy>-6-<(4-methoxybenzyloxy)methyl>-7-methyl-3-<(trimethylsilyl)methyl>-2,6-octadienoate 
• 148675-59-6 ethyl (2S)-2-<(t-butyldimethylsilyl)oxy>-4-<(4-methoxybenzyloxy)methyl>-5-methyl-4-hexenoate 

Relevant academic research and scientific papers

Zeolite β-Induced Rearrangement of Alkoxybenzyl Allyl Ethers to Aldehydes and Ketones. 5.1 Variation of the Allylic Moiety

Allylic PMB ethers rearranged in the presence of zeolite β to form 4-arylbutanals or 5-arylpentanones depending on the substituent pattern of the allylic moiety. Best results were obtained with substrates carrying simple substituents in the allylic 2-posi

New synthesis of a taxol A-ring system

The optically active taxol A-ring unit 3 was synthesized in 11 steps from 2-isopropyl-2-propenol. The stereogenic centers were introduced via the asymmetric glyoxylate-ene reaction and the Sharpless asymmetric epoxidation reaction.