14888-58-5Relevant academic research and scientific papers
Method of making carbonyl compounds
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Page/Page column 3-4, (2008/06/13)
A method of making a carbonyl compound comprises contacting a compound comprising a secondary hydroxyl group with a basic metal oxide catalyst at a temperature sufficient to maintain the compound comprising a secondary hydroxyl group in a vapor phase.
Organolipic substance
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, (2008/06/13)
Described is the compound of the Formula (2R/S, 3R/S)-3-Methyl-4-[(E,1R/S,2R/S,6R/S,7R/S)tricyclo[5.2.1.02,6]dec-4-en-8-ylidene]butan-2-ol, wherein respectively independently from each other the following applies: (2R/S, 3R/S) means (2R,3R), (2R,3S), (2S,3R) or (2S,3S) and (E,1R/S,2R/S,6R/S,7R/S) means (E,1R,2R,6R,7R) or (E,1S,2S,6S,7S). This compound is excellent for use as a fragrance or flavor compound.
A synthesis of hirsutene: a simple route via β-enolization
Dawson, Brian A.,Ghosh, Ashim K.,Jurlina, Jeffrey L.,Ragauskas, Arthur J.,Stothers, J. B.
, p. 2521 - 2525 (2007/10/02)
A simple sequence from dicyclopentadiene to the cis,anti,cis-tricyclopentanoid carbon skeleton of the hirsutanes is described.A key step employs a β-enolate rearrangement to generate the ring system having the desired stereochemistry.The route to the requisite ketone for this rearrangement utilizes efficient ring expansion via homoketonization.
Homoenolisation: a Simple Route to Hirsutene
Dawson, Brian A.,Ghosh, Ashim K.,Jurlina, Jeffrey L.,Stothers, J. B.
, p. 204 - 205 (2007/10/02)
A sequence leading from dicyclopentadiene to the cis,anti,cis-tricyclopentane ring system of the hirsutanes is described in which the key step utilizes rearrangement by homoenolisation to generate the carbon skeleton with the requisite stereochemistry.
