149091-76-9

Upstream product

• 144811-27-8 <1R-(1α,2α,3β,4α,5α)>-2-(Benzyloxy)-1-(hydroxymethyl)-3,4-bis(methoxymethoxy)-6-oxabicyclo<3.1.0>hexane 

Downstream Products

• 147237-44-3 N'-(2,3,4,6-Tetra-O-benzyl-α-D-glucopyranosyl)-N-<<1R-(1α,2β,3α,4β,5β)>-1-(hydroxymethyl)-1,2,3,4-tetrahydroxycyclopent-5-yl>thiourea 
• 147237-45-4 1-Deoxy-1-<<<3aR-(3aα,4α,5β,6α,6aα)>-4-(hydroxymethyl)-3a,5,6,6a-tetrahydro-4,5,6-trihydroxy-4H-cyclopentoxazol-2-yl>amino>-2,3,4,6-tetra-O-benzyl-α-D-glucopyranose 
• 154540-30-4 <1R-(1α,2β,3α,4β,5β)>-5-Acetamido-1,3,4-triacetoxy-1-(acetoxymethyl)-2-(benzyloxy)cyclopentane 
• 149091-77-0 <1R-(1α,2β,3α,4β,5β)>-5-Acetamido-2-(benzyloxy)-1-(hydroxymethyl)-3,4-bis(methoxymethoxy)-1-cyclopentanol 
• 132729-37-4 trehazolin 
• 160799-84-8 (1R,2R,3S,4R,5S)-2-Amino-5-benzyloxy-1-hydroxymethyl-3,4-bis-methoxymethoxy-cyclopentanol 

Relevant academic research and scientific papers

Synthesis and absolute configuration of trehazolin aminocyclitol moiety

Optically active [1R(1α,2β,3α,4β,5β)]-5-acetamide-1-acetoxymethyl-1,2, 3,4-tetraacetoxycyclopentane 2 was synthesized from D-glucose. Compound 2 was identical in all respects with the hexaacetate derived from the natural trehazolin aminocyclito

Syntheses of trehazolin, trehalamine, and the aminocyclitol moiety of trehazolin: Determination of absolute configuration of trehazolin

The syntheses and determination of the absolute configuration of trehazolin (1), its aglycon (trehalamine (3), and its aminocyclitol hexaacetate moiety (5) are described. An important intermediate, optically active epoxide 16α, was obtained from an 11-ste