160799-84-8Relevant articles and documents
Syntheses of trehazolin, trehalamine, and the aminocyclitol moiety of trehazolin: Determination of absolute configuration of trehazolin
Kobayashi,Miyazaki,Shiozaki
, p. 813 - 822 (2007/10/02)
The syntheses and determination of the absolute configuration of trehazolin (1), its aglycon (trehalamine (3), and its aminocyclitol hexaacetate moiety (5) are described. An important intermediate, optically active epoxide 16α, was obtained from an 11-ste
Synthesis and absolute configuration of trehazolin aminocyclitol moiety
Kobayashi, Yoshiyuki,Miyazaki, Hideki,Shiozaki, Masao
, p. 1505 - 1506 (2007/10/02)
Optically active [1R(1α,2β,3α,4β,5β)]-5-acetamide-1-acetoxymethyl-1,2, 3,4-tetraacetoxycyclopentane 2 was synthesized from D-glucose. Compound 2 was identical in all respects with the hexaacetate derived from the natural trehazolin aminocyclito