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149091-92-9

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149091-92-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 149091-92-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,4,9,0,9 and 1 respectively; the second part has 2 digits, 9 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 149091-92:
(8*1)+(7*4)+(6*9)+(5*0)+(4*9)+(3*1)+(2*9)+(1*2)=149
149 % 10 = 9
So 149091-92-9 is a valid CAS Registry Number.
InChI:InChI=1/C16H26N5O18P3/c17-13-7-14(19-3-18-13)21(4-20-7)15-12(39-42(31,32)33)9(5(1-22)34-15)36-16-8(24)11(38-41(28,29)30)10(6(2-23)35-16)37-40(25,26)27/h3-6,8-12,15-16,22-24H,1-2H2,(H2,17,18,19)(H2,25,26,27)(H2,28,29,30)(H2,31,32,33)/t5-,6-,8-,9-,10-,11-,12-,15-,16-/m1/s1

149091-92-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name [(2R,3R,4R,5R)-2-(6-aminopurin-9-yl)-4-[(2R,3R,4R,5R,6R)-3-hydroxy-6-(hydroxymethyl)-4,5-diphosphonooxyoxan-2-yl]oxy-5-(hydroxymethyl)oxolan-3-yl] dihydrogen phosphate

1.2 Other means of identification

Product number -
Other names C16H26N5O18P3

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:149091-92-9 SDS

149091-92-9Upstream product

149091-92-9Downstream Products

149091-92-9Relevant articles and documents

IP3 Receptor-Ligand. 1: Synthesis of Adenophostin A

Hotoda, Hitoshi,Takahashi, Masaaki,Tanzawa, Kazuhiko,Takahashi, Shuji,Kaneko, Masakatsu

, p. 5037 - 5040 (1995)

Adenophostin A, a potent IP3 receptor-agonist, was synthesized.The basic skeleton with 3'-O-(α-D-glucosyl)adenosine was constructed by AgClO4-γ-collidine-promoted glycosylation employing 2-O-benzyl-3,4,6-tri-O-acetyl-α-D-glucopyranosyl bromide

Adenophostin A and analogues modified at the adenine moiety: Synthesis, conformational analysis and biological activity

Borissow, Charles N.,Black, Steven J.,Paul, Michael,Tovey, Stephen C.,Dedos, Skarlatos G.,Taylor, Colin W.,Potter, Barry V. L.

, p. 245 - 252 (2005)

The synthesis of adenophostin A (2) and two analogues [etheno adenophostin (4) and 8-bromo adenophostin (5)] modified at the adenine moiety, is reported. A combination of NMR analysis and molecular modelling was used to compare their structures in solutio

Synthesis of adenophostin A and congeners modified at glucose

Marwood, Rachel D.,Riley, Andrew M.,Jenkins, David J.,Potter, Barry V. L.

, p. 1935 - 1947 (2007/10/03)

A convergent route is described to the super-potent lo-wyo-inositol 1,4,5-trisphosphate receptor agonist adenophostin A (2) and analogues 5 and 7, in which the glucose bisphosphate unit is replaced by corresponding xylose bisphosphate and mannose bisphosphate units respectively. Adenosine was converted into its 2′,3′-O-p-methoxybenzylidene derivative 8ab, which was selectively N6-dimethoxytritylated by a transient protection method. 5′-O-Benzylation followed by reductive acetal cleavage gave, after separation from its 3′-O-p-methoxybenzyl isomer, the versatile glycosyl acceptor 5′-O-benzyl-N 6-dimethoxytrityl-2′-O-p-methoxybenzyladenosine 13. Coupling of 13 with selectively protected glucopyranosyl, xylopyranosyl or mannopyranosyl dimethyl phosphites gave the required 3′-O-α-pyranosyl adenosine derivatives. Acidic hydrolysis gave corresponding N6-unprotected triols which were phosphitylated using bis(benzyloxy)(diisopropylamino)phosphine and imidazolium Inflate without further N6-protection. Deprotection gave the target trisphosphates 2,5 and 7. Synthetic adenophostin A (2) was identical with a sample of natural material in all respects. Analogues 5 and 7 will be useful for structure-activity studies on the adenophostins. The Royal Society of Chemistry 2000.

An expeditious route to the synthesis of adenophostin A

Van Straten, Nicole C.R.,Van Der Marel, Gijsbert A.,Van Boom, Jacques H.

, p. 3599 - 3602 (2007/10/03)

Glycosylation of 1,2-O-isopropylidene-5-O-tert-butyldiphenylsilyl-α-D-ribofuranose (8) with ethyl 3,4,6-tri-O-acetyl-2-O-benzyl-1-thio-α/β-D-glucopyranoside (7) under the agency of N-iodosuccinimide and trifluoromethanesulfonic acid (cat.) afforded α-linked dimer 10 in 95% yield. Vorbruggen-type condensation of 12, obtained by deacetonation of 10 and subsequent acetylation, with bis-trimethylsilyl N6-benzoyl adenine gave adenosyl glucoside 13. Protective group manipulations followed by phosphorylation furnished, after deprotection, homogeneous 2 in high overall yield.

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