14918-24-2Relevant articles and documents
Zur Borylierung von Benzol und Naphthalin durch Dehalogenierungsprodukte von Dichlor(diisopropylamino)boran
Meller, Anton,Bromm, Dietmar,Maringgele, Walter,Bohler, Dieter,Elter, Gernot
, p. 11 - 16 (1988)
The formation of the compounds C6H6 * xBN(i-C3H7)2 (x = 1-6) from the reaction of dichloro(diisopropylamino)borane with sodium/potassium alloy in 1,2-dimethoxyethane, has been confirmed by mass spectrometric studies (high resolution, field ionisation and
Visible photocatalysis of novel oxime phosphonates: Synthesis of β-aminophosphonates
Li, Yong-Hong,Wang, Chun-Hai,Gao, Su-Qian,Qi, Feng-Ming,Yang, Shang-Dong
supporting information, p. 11888 - 11891 (2019/10/11)
A novel type of oxime phosphonate was synthesized and used in the intermolecular cascade radical addition reaction of alkenes to access β-aminophosphonates via visible-light-driven N-centered iminyl radical-mediated and redox-neutral selective C-P single-bond cleavage in an active phosphorus radical route. The procedure is characterized by its ability to achieve the construction of Csp3-P and Csp3-N bonds without the requirement for oxidants and bases.
Amide and amine nucleophiles in polar radical crossover cycloadditions: Synthesis of γ-lactams and pyrrolidines
Gesmundo, Nathan J.,Grandjean, Jean-Marc M.,Nicewicz, David A.
supporting information, p. 1316 - 1319 (2015/03/14)
In this work we present a direct catalytic synthesis of γ-lactams and pyrrolidines from alkenes and activated unsaturated amides or protected unsaturated amines, respectively. Using a mesityl acridinium single electron photooxidant and a thiophenol cocata
Palladium-catalyzed cross-coupling of aryl chlorides with alkenylboronic acids with low E/Z isomerization
Thimmaiah, Muralidhara,Zhang, Xiang,Fang, Shiyue
, p. 5605 - 5607 (2008/12/22)
Using a bulky electron-rich monodentate benzoferrocenyl phosphine as supporting ligand, an efficient protocol for stereoselective palladium-catalyzed Suzuki-Miyaura cross-coupling of aryl chlorides with alkenylboronic acids was uncovered. Using this protocol, both trans- and cis-alkenylboronic acids can be coupled with high stereoselectivity giving the corresponding vinylarenes in good to quantitative yields. Electron-poor and -rich aryl chlorides including highly hindered ones are all suitable substrates for the reaction.