149242-65-9Relevant academic research and scientific papers
Kinetic resolution of quaternary and tertiary ss-hydroxy esters
Schipper, Derek J.,Rousseaux, Sophie,Fagnou, Keith
scheme or table, p. 8343 - 8347 (2010/02/28)
Selectivity factors: The resolution of tertiary and secondary alcohols, which arise from ketone and aldehyde aldol additions, proceeds in the presence of (1S, 2R)-N-methylephedrine (see example). The method is technically simple, easily scalable, and prov
The E/Z geometry of the enolate component determines face selection of the aldehyde component in chiral diazaborolidine-directed enantioselective aldol coupling
Corey,Lee
, p. 1737 - 1740 (2007/10/02)
An analysis of the effect of enolate geometry on transition-state energy explains the stereochemistry of aldol reactions of acetate and propionate esters with aldehydes using as reagent the chiral diazaborolidine 1.
