149391-23-1 Usage
General Description
Bis(mercaptocyclohexane)titanium tetrachloride is a chemical compound containing titanium and sulfur. It is commonly used as a catalyst in organic synthesis, particularly in the production of polymers and plastics. BIS(MERCAPTOCYCLOHEXANE)TITANIUM TETRACHLORIDE is a powerful reducing agent and can also be used in the production of specialty chemicals and pharmaceuticals. It is known for its high reactivity and ability to form strong bonds with other compounds, making it a valuable tool in the field of chemical synthesis and industrial applications.
Check Digit Verification of cas no
The CAS Registry Mumber 149391-23-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,4,9,3,9 and 1 respectively; the second part has 2 digits, 2 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 149391-23:
(8*1)+(7*4)+(6*9)+(5*3)+(4*9)+(3*1)+(2*2)+(1*3)=151
151 % 10 = 1
So 149391-23-1 is a valid CAS Registry Number.
InChI:InChI=1/2C6H12S.4ClH.Ti/c2*7-6-4-2-1-3-5-6;;;;;/h2*6-7H,1-5H2;4*1H;/q;;;;;;+4/p-4/r2C6H12S.Cl4Ti/c2*7-6-4-2-1-3-5-6;1-5(2,3)4/h2*6-7H,1-5H2;
149391-23-1Relevant articles and documents
Adducts of titanium tetrachloride with organosulfur compounds. Crystal and molecular structures of TiCl4(C4H8S)2 and (TiCl4)2(CH3SSCH3)
Lewkebandara, T. Suren,McKarns, Peggy J.,Haggerty, Brian S.,Yap, Glenn P. A.,Rheingold, Arnold L.,Winter, Charles H.
, p. 1 - 9 (1998)
Treatment of titanium tetrachloride with a range of organothiols affords adducts of the formula TiCl4(HSR)2 in 77-89% yields. Reaction of titanium tetrachloride with organic sulfides gives sulfide adducts of the formula TiCl4(SR2)2 in 87-98% yields. These complexes are volatile and monomeric with cis-organosulfur ligands. Treatment of titanium tetrachloride with methyl disulfide affords the adduct (TiCl4)2(CH3SSCH3) in 98% yield, which adopts a dinuclear structure with a Ti2Cl8 core and a bridging disulfide ligand. The crystal structures of TiCl4(C4H8S)2 and (TiCl4)2(CH3SSCH3) were determined. The relevance of these observations to the chemical vapor deposition of titanium disulfide and trisulfide films is discussed.