14949-59-8

Usage

Uses

Used in Pigment Production:
Cadmium bis(piperidine-1-carbodithioate) is used as a pigment ingredient for its color-enhancing properties in various industries, such as plastics, ceramics, and paints. Its ability to create vibrant and stable colors makes it a preferred choice for these applications.
Used in Battery Manufacturing:
In the battery industry, cadmium bis(piperidine-1-carbodithioate) serves as a crucial component in the production of cadmium-based batteries. It contributes to the battery's performance and longevity due to its electrochemical properties.
Used in Coating Applications:
Cadmium bis(piperidine-1-carbodithioate) is utilized as a coating material for its corrosion-resistant and protective qualities. It is particularly useful in industries that require durable and long-lasting coatings, such as automotive and aerospace.
Used in Environmental Remediation:
Cadmium bis(piperidine-1-carbodithioate) is employed as an environmental remediation agent due to its strong binding ability to heavy metal ions. This property allows it to effectively remove or reduce the presence of toxic heavy metals in contaminated environments, such as soil and water.
Used in Analytical Chemistry:
In analytical chemistry, cadmium bis(piperidine-1-carbodithioate) is used as a reagent or analytical tool for the detection and measurement of heavy metal ions. Its high affinity for these ions makes it a reliable and sensitive indicator in various analytical techniques.
However, it is important to note that cadmium bis(piperidine-1-carbodithioate) is toxic to humans and the environment. Exposure to high levels can lead to health issues such as kidney damage, lung problems, and cancer. Therefore, proper safety measures must be taken when handling and using this chemical to minimize potential risks.

InChI:InChI=1/2C6H11NS2.Cd/c2*8-6(9)7-4-2-1-3-5-7;/h2*1-5H2,(H,8,9);/q;;+2/p-2

Upstream product

• 873-57-4 sodium piperidinedithiocarbamate 
• 10108-64-2 cadmium(II) chloride 
• 110-89-4 piperidine 
• 75-15-0 carbon disulfide 
• 7440-43-9 cadmium 

Relevant academic research and scientific papers

Aerosol assisted chemical vapor deposition (AACVD) of CdS thin films from heterocyclic cadmium(II) complexes

Abstract Cadmium dithiocarbamato complexes of piperidine (1) and tetrahydroquinoline (2) were synthesized and characterized by elemental analysis, FT-IR spectroscopy, NMR and TGA analyses. The X-ray single crystal structure of bis(piperidinedithiocarbamato)cadmium(II) complex (1) was determined. The synthesized compounds were used as single source precursors to deposit CdS films on glass substrates at 350, 400 and 450 °C using the aerosol assisted chemical vapor deposition (AACVD) method. The surface morphology and the size of the CdS films were determined by AFM and SEM analyses; the crystalline phases by p-XRD analyses and the elemental composition by EDX measurements. The particle sizes were found to be in the range between 50-110 nm and 100-220 nm for complex (1) and (2), respectively. The electronic properties of the CdS films were analyzed by UV-Vis and Raman spectroscopic methods. Results revealed that the morphology, size and composition of the films are influenced by the deposition temperature.

Synthesis of multi-podal CdS nanostructures using heterocyclic dithiocarbamato complexes as precursors

Bis(dipiperidinyldithiocarbamato)cadmium(II) (1) and bis(ditetrahydroquinolinyldithio-carbamato)cadmium(II) (2) were used as precursors for the synthesis of oleylamine (OA), decylamine (DA) and dodecylamine (DDA) capped CdS nanoparticles. The optical properties of these particles have been studied. The absorption spectra for the amine capped CdS particles are blue shifted in relation to the bulk material. The corresponding photoluminescence spectra show a narrow band edge emission. High quality crystalline CdS particles of different shapes, ranging from short nanorods and elongated nanorods (rods, bipods, tripods and tetrapods) to nanocubes were obtained when the reaction temperature was varied between 180 and 270 C. A decrease in the length of the rods and bipodal nanoparticles was observed with an increase in the length of the chain of the amine (capping agent) used. The p-XRD patterns revealed the hexagonal phase of CdS to be dominant in all the samples. Infra-red studies suggest that the mode of bonding of the amines (oleylamine, decylamine and dodecylamine) on the CdS nanoparticle surfaces is through electron donation from the nitrogen atoms.

Composition and Structure of Complexes in Magnetically Diluted Systems of Copper(II) Dithiocarbamates Cu/M(Dtc)2 (M = Zn, Cd, Hg)

The magnetically diluted complexes Cu/M(Dtc)2 (where M = Zn, Cd, or Hg, and Dtc is the dibutyl-, pentamethylene-, hexamethylene-, or morpholinedithiocarbamate ligand) were studied by EPR. In these systems, copper(II) forms four types of complexes: the mononuclear Cu(Dtc)2 complexes, the CuM(Dtc)4 dimers, and some heteronuclear species resulting from the substitution of one copper atom for a metal atom in the binuclear or mononuclear parts of the adduct-like polynuclear complexes M2(Dtc)4 · nM(Dtc)2 (n = 1-4). The geometry of the copper(II) coordination polyhedra is discussed for all the complexes identified. Structural instability of some of these magnetically diluted systems is attributed to lability of the polynuclear species.

THE DIRECT ELECTROCHEMICAL SYNTHESIS OF DIALKYLDITHIOCARBAMATE AND DIETHYLDITHIOPHOSPHATE COMPLEXES OF MAIN GROUP AND TRANSITION METALS

Dialkyldithiocarbamate derivatives (R2NCS2)nM of a number of metals (M=Fe, Co, Ni, Cu, Ag, Zn, Cd, In, Tl) have been synthesised in good yield by electrochemical oxidation of appropriate sacrificial anodes in non-aqueous solutions of either the corresponding tetraalkylthiuran disulphide (R2NCS2)2 (R=Me, Et) or a mixture of carbon disulphide plus the secondary amine R2NH (R=Et, i-Pr; R2NH=piperidine).Similar experiments with solutions of (EtO)2P(S)SH (=HL) gave MLn* derivatives (M=Fe, Co, Ni, Cu, Ag, Au, Zn, Cd, Hg, Ga, In, Tl) while in the presence of HL+1,10-phenanthroline, MLn.phen derivatives were obtained for M=V, Mn, Fe, Co, Zn, and Ga.