14949-59-8Relevant articles and documents
Aerosol assisted chemical vapor deposition (AACVD) of CdS thin films from heterocyclic cadmium(II) complexes
Mlowe, Sixberth,Nyamen, Linda D.,Ndifon, Peter T.,Malik, M. Azad,Raftery, James,O'Brien, Paul,Revaprasadu, Neerish
, p. 181 - 187 (2015)
Abstract Cadmium dithiocarbamato complexes of piperidine (1) and tetrahydroquinoline (2) were synthesized and characterized by elemental analysis, FT-IR spectroscopy, NMR and TGA analyses. The X-ray single crystal structure of bis(piperidinedithiocarbamato)cadmium(II) complex (1) was determined. The synthesized compounds were used as single source precursors to deposit CdS films on glass substrates at 350, 400 and 450 °C using the aerosol assisted chemical vapor deposition (AACVD) method. The surface morphology and the size of the CdS films were determined by AFM and SEM analyses; the crystalline phases by p-XRD analyses and the elemental composition by EDX measurements. The particle sizes were found to be in the range between 50-110 nm and 100-220 nm for complex (1) and (2), respectively. The electronic properties of the CdS films were analyzed by UV-Vis and Raman spectroscopic methods. Results revealed that the morphology, size and composition of the films are influenced by the deposition temperature.
Composition and Structure of Complexes in Magnetically Diluted Systems of Copper(II) Dithiocarbamates Cu/M(Dtc)2 (M = Zn, Cd, Hg)
Ivanov,Mitrofanova,Rodina
, p. 570 - 574 (2008/10/08)
The magnetically diluted complexes Cu/M(Dtc)2 (where M = Zn, Cd, or Hg, and Dtc is the dibutyl-, pentamethylene-, hexamethylene-, or morpholinedithiocarbamate ligand) were studied by EPR. In these systems, copper(II) forms four types of complexes: the mononuclear Cu(Dtc)2 complexes, the CuM(Dtc)4 dimers, and some heteronuclear species resulting from the substitution of one copper atom for a metal atom in the binuclear or mononuclear parts of the adduct-like polynuclear complexes M2(Dtc)4 · nM(Dtc)2 (n = 1-4). The geometry of the copper(II) coordination polyhedra is discussed for all the complexes identified. Structural instability of some of these magnetically diluted systems is attributed to lability of the polynuclear species.