149508-60-1

Upstream product

• 119197-24-9 3-chloro-4,4,4-trifluoro-2-phenyl-but-2-enal 
• 75-08-1 ethanethiol 
• 20733-13-5 ethanethiolate 

Downstream Products

• 1234701-84-8 2-(3-ethylsulfanyl-4,4,4-trifluoro-1-hydroxy-2-phenylbut-2-enyl)-cyclohex-2-en-1-one 
• 136000-21-0 ((E)-2-Ethylsulfanyl-3,3,3-trifluoro-propenyl)-benzene 
• 136000-20-9 [(1Z)-2-(ethylthio)-3,3,3-trifluoro-1-propenyl]benzene 

Relevant academic research and scientific papers

A convenient one-pot synthesis of β-trifluoromethyl) allylaminophosphonic and benzylaminophosphonic acids

The reductive condensation of aminoalkylphosphonic acids with*β-chloro- or*β-ethylthio-(*β- trifluoromethyl)acroleins leads to secondary (trifluoromethyl) allylaminophosphonic acids in moderate to good yields. The method appears to be useful for the prepa

Synthesis of trifluoromethylalkenes and alkynes. Trifluoromethyl captodative olefins

β-ethylthio-β-trifluoromethylketones 3 and aldehydes 4 are easily prepared from β-chloroolefines 5 and 6. Trifluoromethylalkynes 7 and captodative alkenes 8 are obtained by reaction of KOH on aldehydes 6 or 4.