136000-20-9

Upstream product

• 2003-07-8 [2-bromo-3,3,3-trifluoro-1-propenyl]benzene 
• 75-08-1 ethanethiol 
• 119197-24-9 3-chloro-4,4,4-trifluoro-2-phenyl-but-2-enal 
• 383-64-2 S-ethyl trifluoroacetate 
• 16721-45-2 triphenyl(phenylmethylene)phosphorane 
• 149508-60-1 2-phenyl-3-ethylthio-4,4,4-trifluoromethyl-but-2-en-1-al 

Downstream Products

• 76280-44-9 (E)-(3,3,3-trifluoroprop-1-ene-1,2-diyl)dibenzene 

Relevant academic research and scientific papers

New approach to the synthesis of trifluoromethylvinyl sulfides

Nucleophilic substitution reaction of halogen atom in β-chloro-and β-bromo-β-trifluoromethylstyrenes by thiolates was studied. Stereo-and regioselectivity of the reaction with respect to the electronic and sterical properties of substituents in the aromat

Short and efficient preparation of trifluoromethyl vinyl sulphides

S-Alkyl trifluorothioacetate 2 reacts with stabilized and non-stabilized phosphoranes 1 to afford a new and general route to a wide range of trifluoromethyl vinyl sulphides 3. Until now, no general methods allowed the preparation of these interesting comp

Synthesis of trifluoromethylalkenes and alkynes. Trifluoromethyl captodative olefins

β-ethylthio-β-trifluoromethylketones 3 and aldehydes 4 are easily prepared from β-chloroolefines 5 and 6. Trifluoromethylalkynes 7 and captodative alkenes 8 are obtained by reaction of KOH on aldehydes 6 or 4.