149530-69-8

Basic information

• Product Name: Dimethyl-(1,1-dimethylethyl)-(4-methylphenyl)-silan
• Synonyms: Dimethyl-(1,1-dimethylethyl)-(4-methylphenyl)-silan
• CAS NO: 149530-69-8
• Molecular Weight: 206.403
• Mol File: 149530-69-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Dimethyl-(1,1-dimethylethyl)-(4-methylphenyl)-silan(CAS DataBase Reference)
• NIST Chemistry Reference: Dimethyl-(1,1-dimethylethyl)-(4-methylphenyl)-silan(149530-69-8)
• EPA Substance Registry System: Dimethyl-(1,1-dimethylethyl)-(4-methylphenyl)-silan(149530-69-8)

Safety Data

• Hazardous Substances Data: 149530-69-8(Hazardous Substances Data)

Upstream product

• 86318-61-8 (tert-butyldimethylsilyl)acetylene 
• 78-79-5 isoprene 
• 72726-46-6 tert-butyl(dimethyl)(phenylseleno)silane 
• 108-88-3 toluene 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 4199-04-6 (4-methylphenyl)pentamethyldisilane 
• 106-38-7 para-bromotoluene 
• 57340-42-8 2-Trimethylsilyl-4-methylisobutyldimethylsilylbenzol 

Downstream Products

• 149530-70-1 (4-Brommethylphenyl)-(1,1-dimethylethyl)-dimethylsilan 

Relevant articles and documents

P-Silylation of Arenes via Organic Photoredox Catalysis: Use of p-Silylated Arenes for Exclusive o-Silylation, o-Acylation, and o-Alkylation Reactions

Photocatalytic regiospecific p-silylation of arenes has been achieved by the coupling of in situ generated silyl radical with arene radical cation. The strategy involves reductive activation of PhSe-SiR3 and single electron transfer from the electron rich

Synthesis of new 7-benzofuranmethanamines as heterocyclic analogues of the squalenepoxidase-inhibitor Butenafine

Selected title compounds (6a-f, 7a-d) were synthesized by RedAl(R)-reduction of the carboxamides 4a-f and 5a-d, easily available from the corresponding (2,3-dihydro-)7-benzofurancarboxylic acids 1a-f or 2a-d, respectively. For practical reasons, the preparation of the 2,3-dihydro-2-methyl-7-benzofuranmethanamines 6h-k with varied N-substitution by alkylation of the N-methyl-benzofuranmethanamine 6g with preformed aralkylbromides 9a-d was preferred.