14975-23-6Relevant articles and documents
The reaction of methylphosphine with carbon monoxide borane
Malone,Parry
, p. 176 - 177 (1967)
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Synthesis, photoelectron spectroscopy and quantum chemical study of kinetically unstabilized phosphines complexed by borane
Nemeth, Balazs,Khater, Brahim,Veszpremi, Tamas,Guillemin, Jean-Claude
, p. 3526 - 3535 (2009)
Ethynyl- and allenylphosphine-boranes have been prepared by addition at low temperature of borane on the free phosphine. Purification was performed by selective trapping in vacuo and the complexes were characterized by NMR and infrared spectroscopy and ma
P-H bond activation of primary phosphine-boranes: Access to α-hydroxy and α,α′-dihydroxyphosphine-borane adducts by uncatalyzed hydrophosphination of carbonyl derivatives
Bourumeau, Karine,Gaumont, Annie-Claude,Denis, Jean-Marc
, p. 205 - 213 (2007/10/03)
Primary P-phenyl and P-methyl phosphine-boranes 1 and 2 are prepared by complexation of the free phosphines with BH3 · SMe2. They are stable and can be purified by distillation. Under basic conditions, they lead selectively to secondary alkylphosphine-boranes and under neutral conditions to the corresponding mono- and bis-hydroxyphosphine-boranes 5 and 6. All these new compounds are purified by chromatography on silica gel. A competitive hydroboration induced by the decomplexation of BH3 is observed as a minor process. Conditions for the decomplexation of phosphine-borane adducts are presented.