150072-18-7Relevant academic research and scientific papers
Bis(benzyldi-2-pyridylamine)-η2,η'2-(s-trans-isoprene)dicopper(I) bistrifluoromethanesulfonate. A stable CuI-diene complex
Song, Lin,Trogler, William C.
, p. 271 - 275 (1993)
Addition of benzyldi-2-pyridylamine and isoprene to a solution of 2*C6H6 in THF yields Cu22(μ-C5H8)(O3SCF3)2, the title complex.This complex crystallizes in the triclinic space group P with a = 11.721(4) Angstroem, b = 14.099(4) Angstroem, c = 14.179(4) Angstroem, α = 80.01(2) deg, β = 78.17(2) deg,γ = 71.80(2) deg, V = 2063.6 Angstroem3, and Z = 2.The structure, which contains disordered triflate ligands, converged to an R = 0.086 and Rw = 0.132 for 2887 reflections of I > 3?(I0).It exhibits the isoprene ligand in the s-trans configuration chelating η2 to both CuI atoms.
