26422-90-2

Basic information

• Product Name: 2-Pyridinamine, N-(phenylmethyl)-N-2-pyridinyl-
• CAS NO: 26422-90-2
• Molecular Formula: C17H15N3
• Molecular Weight: 261.326
• Mol File: 26422-90-2.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: 2-Pyridinamine, N-(phenylmethyl)-N-2-pyridinyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Pyridinamine, N-(phenylmethyl)-N-2-pyridinyl-(26422-90-2)
• EPA Substance Registry System: 2-Pyridinamine, N-(phenylmethyl)-N-2-pyridinyl-(26422-90-2)

Safety Data

• Hazardous Substances Data: 26422-90-2(Hazardous Substances Data)

Upstream product

• 1202-34-2 di(pyridin-2-yl)amine 
• 100-44-7 benzyl chloride 
• 109-09-1 2-chloropyridine 
• 100-46-9 benzylamine 
• 109-04-6 2-bromo-pyridine 
• 123368-97-8 2-[N-methyl-N-(pyridin-2-yl)amino]pyridine 
• 100-39-0 benzyl bromide 

Downstream Products

• 1616245-51-2 [Ni(μ-Cl){2,2′-dipyridyl-N-benzylamine}Cl]2 
• 1604045-42-2 Pd^(II)Me(2,2′-dipyridyl-N-benzylamine)Cl 
• 868159-22-2 Pd((2,2'-dipyridyl)benzilamine)Cl₂ 
• 150072-18-7 {bis(benzyldi-2-pyridylamine)-η2,η'2-(s-trans-isoprene)dicopper(I)} bistrifluoromethanesulfonate 

Relevant articles and documents

The Role of an Alkyl–Phenyl Spacer on the Reactivity of Novel Platinum(II) Complexes with Thiourea Nucleophiles

The presented work, submitted as a paper, deals with the substitution reactions of mononuclear and dinuclear platinum(II) complexes of di-2-pyridylaminodiaquaplatinum(II), (Pt1); di-2-pyridylaminomethylbenzenediaquaplatinum(II), (Pt2); 1,2-bis(di-2-pyridy

ELECTROCHEMICAL ALKYLATION OF 2,2'-DIPYRIDYLAMINE

A method was developed for preparation of alkyl-(2,2'-dipyridyl)amines, consisting of the reaction of alkyl halides with the N anion electrochemically generated from 2,2'-dipyridylamine.The alkylation occurs regiospecifically, and CH2Cl2 can also be used as the methylating agent.Complexes of alkyl-(2,2'-dipyridyl)amines with Pd(2+) and Cu(2+) salts were obtained.

Non-conventional synthesis and photophysical studies of platinum(ii) complexes with methylene bridged 2,2′-dipyridylamine derivatives

Methylene bridged 2,2′-dipyridylamine (dpa) derivatives and their metal complexes possess outstanding properties due to their inherent structural flexibility. Synthesis of such complexes typically involves derivatization of dpa followed by coordination on metals, and may not always be very efficient. In this work, an alternative synthetic approach, involving the derivatization step after-rather than prior to-coordination of dpa on metal center, is proposed and applied to synthesis of a number of platinum(ii) complexes with substituted benzyldi(2-pyridyl)amines. Comparison with the more conventional synthetic route reveals greater efficiency and versatility of the proposed approach. The obtained complexes are not luminescent in solution at room temperature, but display blue phosphorescence emission (ca. 415 nm) with the lifetimes of μs order in glassy matrix at 77 K, with additional green (ca. 485 nm) and relatively long living (τ = 3.7 ms) emission in the case of iodine substituted derivative.

Ruthenium and Iridium Dipyridylamine Catalysts for the Efficient Synthesis of γ-Valerolactone by Transfer Hydrogenation of Levulinic Acid

The selective and efficient transfer hydrogenation of levulinic acid into γ-valerolactone was performed with new ruthenium and iridium catalysts bearing dipyridylamine (dpa) ligands. Reactions were performed in the presence of formic acid and triethylamine using catalyst loading as low as 0.05 mol % with a ruthenium complex (turnover number = 1980). Recyclability of a ruthenium catalyst was demonstrated by running 6 consecutive reactions in almost quantitative yields.