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1502-24-5

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1502-24-5 Usage

Chemical Properties

Clear colourless liquid

Check Digit Verification of cas no

The CAS Registry Mumber 1502-24-5 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,5,0 and 2 respectively; the second part has 2 digits, 2 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 1502-24:
(6*1)+(5*5)+(4*0)+(3*2)+(2*2)+(1*4)=45
45 % 10 = 5
So 1502-24-5 is a valid CAS Registry Number.
InChI:InChI=1/C8H16O/c1-6-4-3-5-8(9)7(6)2/h6-9H,3-5H2,1-2H3

1502-24-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 2,3-dimethylcyclohexan-1-ol

1.2 Other means of identification

Product number -
Other names 3-Hydroxy-1.2-dimethyl-cyclohexan

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1502-24-5 SDS

1502-24-5Relevant articles and documents

Stereoselective alkane hydroxylations by metal salts and m-chloroperbenzoic acid

Nam, Wonwoo,Ryu, Ju Yeon,Kim, Inwoo,Kim, Cheal

, p. 5487 - 5490 (2002)

Simple metal (M=Mn, Fe, Co) perchlorates associated with m-chloroperbenzoic acid are able to conduct stereoselective alkane hydroxylations via a mechanism involving metal-based oxidants; the catalytic activity of the metal salts is in the order of Co(ClO4)2>Mn(ClO4)2>Fe (ClO4)2.

Stereospecific Alkane Hydroxylation with H2O2 Catalyzed by an Iron(II)-Tris(2-pyridylmethyl)amine Complex

Kim, Cheal,Chen, Kui,Kim, Jinheung,Que, Lawrence

, p. 5964 - 5965 (1997)

-

Stereoselective oxidation of alkanes with: M -CPBA as an oxidant and cobalt complex with isoindole-based ligands as catalysts

Nesterova, Oksana V.,Kopylovich, Maximilian N.,Nesterov, Dmytro S.

, p. 93756 - 93767 (2016/10/21)

Two complexes with isoindole-core ligands of general formula [M{C6H4C(NH2)NC(ONCMe2)2}2](NO3)2 (M = Co for 1 and M = Ni for 2) were studied as catalysts for the mild stereoselective alkane oxidation with m-chloroperbenzoic acid (m-CPBA) as an oxidant and cis-1,2-dimethylcyclohexane (cis-1,2-DMCH) as a main model substrate. Complex 1 disclosed a pronounced activity, with high retention of stereoconfiguration of substrates (>98% for cis-1,2-DMCH) and highest cis/trans ratio of tertiary alcohols (products) of 56, under mild conditions. The best achieved yields of tertiary cis-alcohols were of 13.7 and 50.5%, based on the substrate (cis-1,2-DMCH) and the oxidant (m-CPBA) respectively. Kinetic experiments, high bond and stereoselectivity parameters, kinetic isotope effect of 7.2(2) in the oxidation of cyclohexane, and incorporation of 18O from H218O support the involvement of CoIVO high-valent metal-oxo intermediates as main C-H attacking species.

Catalytic oxidation of alkanes by a (salen)osmium(VI) nitrido complex using H2O2 as the terminal oxidant

Chen, Man,Pan, Yi,Kwong, Hoi-Ki,Zeng, Raymond J.,Lau, Kai-Chung,Lau, Tai-Chu

supporting information, p. 13686 - 13689 (2015/09/02)

The osmium(vi) nitrido complex, [OsVI(N)(L)(CH3OH)]+ (1, L = N,N′-bis(salicylidene)-o-cyclohexyldiamine dianion) is an efficient catalyst for the oxidation of alkanes under ambient conditions using H2O2 as the oxidant. Alkanes are oxidized to the corresponding alcohols and ketones, with yields up to 75% and turnover numbers up to 2230. Experimental and computational studies are consistent with a mechanism that involves O-atom transfer from H2O2 to [OsVI(N)(L)]+ to generate an [OsVIII(N)(O)(L)]+ active intermediate.

Catalytic oxidation of alkanes by iron bispidine complexes and dioxygen: Oxygen activation versus autoxidation

Comba, Peter,Lee, Yong-Min,Nam, Wonwoo,Waleska, Arkadius

supporting information, p. 412 - 414 (2014/01/06)

Organic substrates (specifically cis-1,2-dimethylcyclohexane, DMCH) are oxidized by O2 in the presence of iron(ii)-bispidine complexes. It is shown that this oxidation reaction is not based on O2 activation by the nonheme iron catalysts as in Nature but due to a radical-based initiation, followed by a radical- and ferryl-based catalytic reaction.

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