15051-71-5Relevant articles and documents
BF3-Assisted Reactions of 1-Benzothiophen-3(2H)-one with Various Ketones: a Convenient Entry to 2-Methylene-1-benzothiophen-3(2H)-one and/or 6H-Di[1]benzothieno[3,2-b:2,3-e]pyran Derivatives
Fraleoni, Alessandro,Zanirato, Paolo
, p. 2401 - 2420 (2007/10/03)
The title compounds were obtained by BF3-assisted reactions of 1-benzothiophen-3(2H)-one with nine ketones in diethyl ether at room temperature in moderate to high yields. The pyran 1 and ylidene 2 ratios prove to be dependent upon electronic and steric f