151052-25-4

Upstream product

• 1184181-89-2 (R)-5-(benzyloxy)pent-3-yn-2-ol 
• 65844-86-2 5-(benzyloxy)pent-3-yn-2-one 
• 171011-84-0 5-(Benzyloxy)-3-pentyn-2-ol 
• 171011-70-4 (S)-4-(tert-butyl-dimethyl-silanyloxy)-pent-2-yn-1-ol 
• 151052-22-1 (Z)-(R)-4-(tert-Butyl-dimethyl-silanyloxy)-pent-2-en-1-ol 
• 151052-19-6 (Z)-(R)-4-(tert-Butyl-dimethyl-silanyloxy)-pent-2-enoic acid methyl ester 
• 100-39-0 benzyl bromide 
• 151052-23-2 ((Z)-(R)-4-Benzyloxy-1-methyl-but-2-enyloxy)-tert-butyl-dimethyl-silane 

Downstream Products

• 151052-27-6 2,2,2-Trichloro-acetimidic acid (Z)-(R)-4-benzyloxy-1-methyl-but-2-enyl ester 
• 113123-28-7 (R)-1-((2S,3R)-3-((benzyloxy)methyl)oxiran-2-yl)ethan-1-ol 

Relevant academic research and scientific papers

First stereoselective total synthesis and reconfirmation of absolute structure of nonenolide (?)-stagonolide D

The first stereoselective total synthesis of nonenolide (?)-stagonolide D has been accomplished. Midland Alpine borane reduction to install hydroxyl group at C4, Henbest epoxidation to introduce epoxide stereoselectively between C7 and C8, Yamaguchi ester

The regio- and stereospecific intermolecular dehydrative alkoxylation of allylic alcohols catalyzed by a gold(I) N-heterocyclic carbene complex

A 1:1 mixture of [AuCl(IPr)] (IPr=1,3-bis(2,6-diisopropylphenyl)imidazol-2- ylidine) and AgClO4 catalyzes the intermolecular dehydrative alkoxylation of primary and secondary allylic alcohols with aliphatic primary and secondary alcohols to for

Chirality Transfer from Lactic Acid Derivatives via Sigmatropic Rearrangements

Enantiomerically pure lactaldehyde 4 was converted via stereoselective Wittig reactions to the E or Z enoates 5 or 6.These were then transformed into the E and Z allylic trichloroimidates 9 and 13, respectively.Thermal sigmatropic rearrangement of 9