15137-12-9

Upstream product

• 15137-12-9 mer-Rh(C6H5PEt2)3Cl3 
• 124-38-9 carbon dioxide 
• 95348-88-2 (Rh₂Cl₆(P(C₂H₅)2(C₆H₅))3) 
• 1605-53-4 diethyl-phenyl-phosphine 

Downstream Products

• 25504-23-8 RhCl(PEt₂Ph₃)3 
• 15137-12-9 fac-Rh(C₆H₅PEt₂)3Cl₃ 
• 95348-90-6 ((P(C₂H₅)2(C₆H₅))2ClRhCl₃RhCl(P(C₂H₅)2(C₆H₅))2)⁽¹⁺⁾*(B(C₆H₅)4)^(1-) 
• 95348-91-7 (RhCl₃(P(C₂H₅)2C₆H₅)2(H₂O)) 
• 95348-88-2 (Rh₂Cl₆(P(C₂H₅)2(C₆H₅))3) 

Relevant academic research and scientific papers

Mechanism of Formation of Peroxocarbonates RhOOC(O)O(Cl)(P)3 and Their Reactivity as Oxygen Transfer Agents Mimicking Monooxygenases. the First Evidence of CO2 Insertion into the O-O Bond of Rh(η2-O2) Complexes

Extended labeling experiments have shown that formation of rhodium peroxocarbonate from CO2 and [RhCl(η2-O2(P)3] (P is PEt2Ph or PEtPh2) proceeds through O-O bond cleavage and CO2 insertion. O-transfer to ancillary phosphine ligand to give R3P=O selectively (>85%) involves the Rh-linked O atom of the peroxo group of RhCl(CO4)(P)3.

Tertiary phosphine complexes of rhodium(I) and rhodium(III) chlorides

The most complete series of tertiary phosphine complexes of rhodium yet reported has been prepared. Depending on the particular phosphine and the method of preparation, several different types of complexes may be formed. These include RhCl3(PR