151452-03-8

Basic information

• Product Name: 1-(2-(benzylselanyl)phenyl)ethan-1-one
• Synonyms: 1-(2-(benzylselanyl)phenyl)ethan-1-one
• CAS NO: 151452-03-8
• Molecular Weight: 289.236
• Mol File: 151452-03-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(2-(benzylselanyl)phenyl)ethan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-(benzylselanyl)phenyl)ethan-1-one(151452-03-8)
• EPA Substance Registry System: 1-(2-(benzylselanyl)phenyl)ethan-1-one(151452-03-8)

Safety Data

• Hazardous Substances Data: 151452-03-8(Hazardous Substances Data)

Upstream product

• 6586-11-4 sodium benzeneselenolate 
• 551-93-9 2-aminoacetophenone 
• 1441-75-4 1-(2-selenocyanatophenyl)ethan-1-one 
• 100-39-0 benzyl bromide 

Downstream Products

• 40193-43-9 3-methyl-1,2-benzoselenazole 
• 1369591-64-9 1-(2-(benzylseleninyl)phenyl)ethanone 

Relevant articles and documents

Metal-free visible light-promoted synthesis of isothiazoles: A catalytic approach for N-S bond formation from iminyl radicals under batch and flow conditions

A sustainable synthesis of isothiazoles has been developed using an α-amino-oxy acid auxiliary and applying photoredox catalysis. This simple strategy features mild conditions, broad scope and wide functional group tolerance representing a new enviromenta

Homolytic substitution by iminyl radical at selenium: A free-radical route to 1,2-benzoselenazoles

Thiohydroxamic esters (3) derived from the O-carboxymethyl oxime derivatives (2) of 2-(benzylseleno)-benzaldehyde (1: R = H), 2-(benzylseleno)acetophenone (1: R = Me) and 2-(benzylseleno)propiophenone (1: R = Et) decompose smoothly, upon irradiation, with the loss of carbon dioxide and formaldehyde to give the 1,2-benzoselenazoles (5). The reaction presumably involves the iminyl radical intermediate (4) which undergoes intramolecular free-radical homolytic substitution at selenium to afford the product (5).