15158-14-2

Basic information

• Product Name: Benzene, 1,3-bis(1-methylethyl)-2-(4-nitrophenoxy)-
• CAS NO: 15158-14-2
• Molecular Formula: C18H21NO3
• Molecular Weight: 299.37
• Mol File: 15158-14-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1,3-bis(1-methylethyl)-2-(4-nitrophenoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,3-bis(1-methylethyl)-2-(4-nitrophenoxy)-(15158-14-2)
• EPA Substance Registry System: Benzene, 1,3-bis(1-methylethyl)-2-(4-nitrophenoxy)-(15158-14-2)

Safety Data

• Hazardous Substances Data: 15158-14-2(Hazardous Substances Data)

Upstream product

• 100-25-4 para-dinitrobenzene 
• 113981-41-2 sodium 2,6-diisopropylphenate 
• 1035347-44-4 2,6-diisopropylphenyl tert-butyldimethylsilyl ether 
• 350-46-9 4-Fluoronitrobenzene 
• 2078-54-8 2,6-diisopropylphenol 
• 100-00-5 4-chlorobenzonitrile 

Relevant articles and documents

P(i-BuNCH2CH2)3N: an efficient promoter for the microwave synthesis of diaryl ethers

With the title proazaphosphatrane as a promoter, the coupling of aryl fluorides with aryl TBDMS ethers under microwave conditions gave moderate to high yields of the desired products at low catalyst loadings and in short times. In this methodology, electron deficient aryl fluorides possessing substituents, such as nitro, cyano, and ester, were coupled with sterically demanding aryl TBDMS ethers as well as with aryl TBDMS ethers bearing a variety of functionalities such as methoxy, halo, and cyano groups.

Displacement of an Aromatic Nitro Group using Phenoxides

1,4-dinitrobenzene undergoes nucleophilic substitution with sodium phenoxide and several hindered 2,6-disubstituted phenoxides to afford diphenyl ethers.