151694-10-9Relevant academic research and scientific papers
In Turn or in Reverse Palladium-Catalyzed Carbonyl Allylation and Diels-Alder Reaction by 2-Methylene-3-buten-1-ol
Masuyama, Yoshiro,Fuse, Manabu,Kurusu, Yasuhiko
, p. 1199 - 1202 (1993)
Using PdCl2(PhCN)2-SnCl2, 2-methylene-3-buten-1-ol causes carbonyl allylation of various aldehydes to afford 1-substituted-3-methylene-4-penten-1-ols, the Diels-Alder reaction of those with dienophiles produces 1-(2-hydroxyethyl)cyclohexenes.Diels-Alder reaction of 2-methylene-3-buten-1-ol with dienophiles followed by carbonyl allylation produces isomeric 1-methylene-2-(hydroxymethyl)cyclohexanes.
