Chemistry Letters p. 1199 - 1202 (1993)
Update date:2022-08-05
Topics:
Masuyama, Yoshiro
Fuse, Manabu
Kurusu, Yasuhiko
Using PdCl2(PhCN)2-SnCl2, 2-methylene-3-buten-1-ol causes carbonyl allylation of various aldehydes to afford 1-substituted-3-methylene-4-penten-1-ols, the Diels-Alder reaction of those with dienophiles produces 1-(2-hydroxyethyl)cyclohexenes.Diels-Alder reaction of 2-methylene-3-buten-1-ol with dienophiles followed by carbonyl allylation produces isomeric 1-methylene-2-(hydroxymethyl)cyclohexanes.
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