1517-71-1Relevant academic research and scientific papers
Novel N-coordinate half-sandwich ruthenium(II) arene complexes bearing sulfonamide fragments: Catalytic activities in the TH of acetophenone derivatives
Kayaci, Nilgün,Dayan, Serkan,Kalaycioglu Ozpozan, Nilgun
, p. 446 - 452 (2015)
Abstract The novel cationic N-coordinate ruthenium(II)/arene complexes (6-10) were prepared from the starting complex [RuCl2(p-cymene)]2 dimer. The structures of the [(p-cymene)RuLCl]Cl (L = N-arenesulfonyl-4,5-dimethyl-o-phenylenedi
Synthesis and catalytic activity of semiconducting p-cymene ruthenium 1,3,4-thiadiazole and 1,2,4-triazole complexes
Serbetci, Zafer
, p. 957 - 960 (2013)
The novel ruthenium(II) complexes containing 5-(pyridin-4-yl)-1,3,4- thiadiazol-2-amine(1) and 4-amino-5-(pyridin-4-yl)-4H-1,2,4-triazole-3-thiol (2) ligands were synthesized and characterized by UV-Vis, IR, NMR, and elemental analysis. The complexes have
Catalytic transfer hydrogenation and anticancer activity of arene-ruthenium compounds incorporating bi-dentate precursors
Chang, Yu-Hsiang,Leu, Wohn-Jenn,Datta, Amitabha,Hsiao, Hung-Chang,Lin, Chia-Her,Guh, Jih-Hwa,Huang, Jui-Hsien
, p. 16107 - 16118 (2015)
Ruthenium based organometallic compounds are presently a subject of great attention as anticancer drugs and appear to work reasonably well on tumor cells. We develop a series of mononuclear arene-ruthenium compounds incorporating N,O and N,N bidentate lig
Ruthenium(II) carbonyl chloride complexes containing pyridine- functionalised bidentate N-heterocyclic carbenes: Synthesis, structures, and impact of the carbene ligands on catalytic activities
Li, Xiao-Wei,Wang, Gao-Feng,Chen, Fei,Li, Yi-Zhi,Chen, Xue-Tai,Xue, Zi-Ling
, p. 280 - 287 (2011)
A series of new ruthenium(II) carbonyl chloride complexes with pyridine-functionalised N-heterocyclic carbenes [Ru(Py-NHC)(CO) 2Cl2], [Py-NHC = 3-methyl-1-(2-pyridyl)imidazol-2-ylidene, 1 (1a and 1b); 3-methyl-1-(2-picoyl)imidazol-2-
Preparation, characterization, and catalytic properties of ruthenium nitrosyl complexes with polypyrazolylmethane ligands
Xu, Hui-Jun,Cheng, Yong,Sun, Jia-Feng,Dougan, Brenda A.,Li, Yi-Zhi,Chen, Xue-Tai,Xue, Zi-Ling
, p. 3851 - 3857 (2008)
Ruthenium(II) nitrosyl complexes with polypyrazolylmethanes, [(Bpm)Ru(NO)Cl3] [Bpm = bis(1-pyrazolyl)methane, 1], [(Bpm*)Ru(NO)Cl3] [Bpm* = bis(3,5-dimethyl-1-pyrazolyl)methane, 2], [(Tpm)Ru(NO)Cl2][P
Synthesis, structures and catalytic activities of ruthenium(ii) carbonyl chloride complexes containing pyridine-functionalised N-heterocyclic carbenes
Cheng, Yong,Xu, Hui-Jun,Sun, Jia-Feng,Li, Yi-Zhi,Chen, Xue-Tai,Xue, Zi-Ling
, p. 7132 - 7140 (2009)
A series of ruthenium(ii) carbonyl chloride complexes with pyridine-functionalised N-heterocyclic carbenes, trans(Cl)- and cis(Cl)-[Ru(Py-NHC)(CO)2Cl2] [Py-NHC = 3-tert-butyl-1-(2-pyridyl)imidazol-2-ylidene, 1a and 1b; 3-n-butyl-1-(2
Quinoline-functionalized N-heterocyclic carbene complexes of iridium: Synthesis, structures and catalytic activities in transfer hydrogenation
Sun, Jia-Feng,Chen, Fei,Dougan, Brenda A.,Xu, Hui-Jun,Cheng, Yong,Li, Yi-Zhi,Chen, Xue-Tai,Xue, Zi-Ling
, p. 2096 - 2105 (2009)
Iridium complexes containing quinoline-functionalized N-heterocyclic carbene (NHC) ligands have been synthesized by the transmetalation route from silver carbene precursors. The silver complexes undergo a facile reaction with [Ir(COD)Cl]2 (COD
In situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[RuCl2(p-cymene)]2 system for transfer hydrogenation reactions
Oezge Oezcan, Emine,Mercan, Deniz,Guerbuez, Nevin,Cetinkaya, Engin,Cetinkaya, Bekir,Oezdemir, Ismail
, p. 699 - 709 (2011)
Hydrogen-transfer reduction processes are attracting increasing interest from synthetic chemists in view of their operational simplicity. In the present study novel ruthenium carbene complexes were generated in situ and tested for their transfer hydrogena
Bis-N-heterocyclic carbene ruthenium(II) carbonyl complexes: Synthesis, structural characterization and catalytic activities in transfer hydrogenation of ketones
Cheng, Yong,Lu, Xiang-Yong,Xu, Hui-Jun,Li, Yi-Zhi,Chen, Xue-Tai,Xue, Zi-Ling
, p. 430 - 437 (2010)
In this contribution, the synthesis and characterization of eight ruthenium(II) carbonyl complexes supported by chelating alkane-bridged bis-N-heterocyclic carbene ligands are reported. The products obtained are analyzed using infrared and NMR spectroscop
Applying Le Chatelier's Principle for a Highly Efficient Catalytic Transfer Hydrogenation with Ethanol as the Hydrogen Source
Weingart, Pascal,Thiel, Werner R.
, p. 4858 - 4862 (2018)
While isopropanol or formic acid derivatives are mainly applied as hydrogen sources in catalytic transfer hydrogenation reactions, there are only a few reports on the use of primary alcohols. In the present communication we report that ecologically benign and cheap ethanol can be applied with a ruthenium(II) that is completely stable against moisture and oxygen. Catalytic transfer hydrogenation is an equilibrium reaction. Therefore, a rapid removal of acetic aldehyde being formed as the product of ethanol oxidation is the key for high conversions. The reaction shows a broad substrate scope and allows the hydrogenation of ketones, aldehydes and imines.
