15189-56-7

Upstream product

• 56-23-5 tetrachloromethane 
• 14285-68-8 decacarbonyldirhenium⁽⁰⁾ 
• 603-35-0 triphenylphosphine 
• 118228-22-1 mer,trans-Re(CO)3(PPh₃)2CHO 
• 27770-64-5 Re₂(CO)8(PPh₃)2 
• 15189-56-7 trans-[chloro-tetracarbonyl-triphenylphosphino-rhenium] 
• 75-09-2 dichloromethane 

Downstream Products

• 113975-87-4 cis-ClRe(CO)4(pip) 
• 603-35-0 triphenylphosphine 
• 27770-64-5 ((P(C₆H₅)3)(CO)3Re(CO))2 

Relevant academic research and scientific papers

Synthesis, characterization and reactivity of dinuclear rhenium complexes containing hemilabile phosphines as ligands: X-ray structures of diax-[Re2(CO)8{κ1(P)-Ph2P(CH2)2CN}2], [

The reaction of [Re2(CO)8(MeCN)2] with cyanoethylphosphines affords mono- and disubstituted compounds where the phosphine ligand is κ1(P)-coordinated. When diallylphosphines are used as ligands, the μ:κ3/s

Synthesis and thermolysis of neutral metal formyl complexes of molybdenum, tungsten, manganese, and rhenium

The possible intermediacy of catalyst-bound formyls in syngas transformations has prompted efforts to prepare and study the chemistry of transition-metal formyl complexes over more than a decade. We have used a mild borohydride in our reactions with metal carbonyl cations and have introduced some variations into the syntheses which allow, in almost all cases, for the pure formyl complex to be precipitated from solution as it is formed. The formyl complexes and their cationic precursors are shown. Seven of the formyls are new; improved procedures have been established for the other four. All but one of the compounds have been isolated.

The Halogenation of Toluene with Sulphuryl Chloride and Dichlorine in the Presence of Transition Metal Complexes

A detailed study has been made of the halogenation of toluene in the presence of a range of transition metal complexes.Both side-chain and ring chlorination are observed, the favoured route depending on the metal complex.Side-chain halogenation, in the presence of and (M= Pd, Pt), has been shown to proceed by a free radical chain reaction in which the metal complex acts solely as an initiator.In the presence of, (M= Mn, Re), , and , ring chlorinated products are formed by a Friedel-Crafts mechanism.

THE USE OF SO2Cl2 IN ORGANOMETALLIC CHEMISTRY. CONVENIENT HIGH YIELD SYNTHESES OF AND (M = Mn or Re)

Depending on the substrate and the reaction conditions, SO2Cl2 is a useful reagent which brings about either chlorination or the formation of cationic species on reaction with transition metal carbonyl complexes.

Associative Substitution Reactions of *Re(CO)5

Studies of competition between substitution and chlorine abstraction reactions of photochemically generated *Re(CO)5 radicals show that substitution proceeds via a second-order associative path and not via CO dissociation.