151954-45-9

Upstream product

• 7677-24-9 trimethylsilyl cyanide 
• 620-23-5 m-tolyl aldehyde 
• 75-77-4 chloro-trimethyl-silane 
• 151-50-8 potassium cyanide 

Downstream Products

• 65148-70-1 3-methylmandelic acid 
• 53313-96-5 α-hydroxy-3-methylbenzeneacetonitrile 
• 53313-96-5 (R)-(+)-α-hydroxy-3-methylphenylacetonitrile 
• 10017-03-5 (S)-(-)-α-hydroxy-3-methylphenylacetonitrile 
• 345961-57-1 2-fluoro-2-(3-methylphenyl)ethanenitrile 
• 53360-88-6 DL-[2-hydroxy-2-(3-methylphenyl)ethyl]amine 
• 77062-84-1 methyl 2-hydroxy-2-(3-methylphenyl)acetate 
• 1424280-46-5 C₂₇H₄₄O₄Si 
• 153275-21-9 [4-(2-Ethyl-5,7-dimethyl-imidazo[4,5-b]pyridin-3-ylmethyl)-2,6-dipropyl-phenoxy]-m-tolyl-acetic acid ethyl ester 
• 160462-34-0 ethyl 2-(2,6-Dipropyl-4-Bromomethyl-Phenoxy)-2-(3-Methylphenyl)Acetate 
• 160462-33-9 ethyl 2-(2,6-dipropyl-4-hydroxymethyl phenoxy)-2-(3-methylphenyl)acetate 
• 151954-61-9 3-<<4-phenyl>methyl>-5,7-dimethyl-2-ethyl-3H-imidazo<4,5-b>pyridine 
• 151954-51-7 3-<<4-phenyl>methyl>-5,7-dimethyl-2-ethyl-3H-imidazo<4,5-b>pyridine 

Relevant academic research and scientific papers

Temperature-induced Sn(II) supramolecular isomeric frameworks as promising heterogeneous catalysts for cyanosilylation of aldehydes

Two novel Sn(II) supramolecular isomeric frameworks, with the identical formula of {(NH2Me2)2[Sn(BDC)(SO4)]}n, Sn-CP-1-α (1) and Sn-CP-1-β (2) (H2BDC=terephthalic acid) were synthesized und

Controlled in situ reaction for the assembly of Cu(ii) mixed-ligand coordination polymers: synthesis, structure, mechanistic insights, magnetism and catalysis

It has been a challenge to decipher the in situ ligand reaction mechanism in assembly processes, involving metals and ligands. The present study shows two crystalline mixed-ligand Cu(ii) coordination polymers isolated by controlled in situ ligand reaction

Four Hybrid Materials Based on Preyssler P5W30 Polyoxometalate and First-Row Transition-Metal Complex

Four Preyssler P5W30 based inorganic-organic hybrids, formulated as {[Cu12(pbtz)2(Hpbtz)2(OH)4(H2O)16][Na(H2O)P5W30O110]}·1

Catalytic cyanosilylation application and antitumor activity in osteosarcoma of a porous Gd(III)-based coordination polymer

Solvothermal reactions of 1, 3, 5-tris (4-carboxyphenyl)-benzene (H3BTB) with Gd(NO3)·6H2O gave rise to a new highly porous coordination polymer {[Gd(BTB)(H2O)](DMF)(H2O)}n (1) having three

A novel silver(I)-Keggin-polyoxometalate inorganic-organic hybrid: A Lewis acid catalyst for cyanosilylation reaction

A novel polyoxometalate (POM) hybrid material based on a Keggin polyanion and silver(I)-organic sheet, namely, [Ag4(apym)4(SiW12O40)]n (1), where apym = 2-aminopyrimidine, has been synthesized under h

Silyl Cyanopalladate-Catalyzed Friedel-Crafts-Type Cyclization Affording 3-Aryloxindole Derivatives

3-Aryloxindole derivatives were synthesized through a Friedel-Crafts-type cyclization. The reaction was catalyzed by a trimethylsilyl tricyanopalladate complex generated in situ from trimethylsilyl cyanide and Pd(OAc) 2. Wide varieties of diethyl phosphates derived from N -arylmandelamides were converted almost quantitatively into oxindoles. When N, N -dibenzylamide was used instead of an anilide substrate, a benzo-fused δ-lactam was obtained. An oxindole product was subjected to substitution reactions to afford 3,3-diaryloxindoles with two different aryl groups.

Constructing a triangular metallacycle with salen-Al and its application to a catalytic cyanosilylation reaction

A triangular metallosalen-based metallacycle was constructed in quantitative yield by the self-assembly of a 180° bis(pyridyl)salen-Al complex and a 60° diplatinum(ii) acceptor in a 1?:?1 stoichiometric ratio. This metallacycle was then successfully used to cyanosilylate a wide range of benzaldehydes with trimethylsilyl cyanide.

PhI(OAc)2-mediated alkoxyoxygenation of β,γ-unsaturated ketoximes: Preparation of isoxazolines bearing two contiguous tetrasubstituted carbons

A PhI(OAc)2-promoted dioxygenation of allyl oximes, including one alkoxylation, has been developed. This reaction can give isoxazoline products bearing two contiguous tetrasubstituted carbons. Various oximes substrates bearing different aryl groups and tetrasubstituted-olefin moieties were compatible with the mild reaction conditions. A two-electron oxidation pathway was proposed based on results of preliminary mechanistic studies.

Method for aldehyde cyanosilylation reaction under conditions of no catalyst or solvent

The invention discloses a method for an aldehyde cyanosilylation reaction under conditions of no catalyst or solvent. In a glove box, aldehyde and trimethylsilyl cyanide are sequentially added to a nuclear magnetic resonance tube, then, the glove box is m

Lewis Acid Mediated Nazarov Cyclization as a Convergent and Enantioselective Entry to C-nor-D-homo-Steroids

A straightforward synthesis of C-nor-D-homo steroids starting from (+)-Wieland–Miescher ketone is reported. This convergent synthetic strategy utilizes a?scalable diastereoselective Nazarov cyclization of functionalized chiral aryl vinyl ketones, allowing for further functionalization. The ability to conduct this key transformation on a multi-gram scale paves the way for the synthesis of a variety of completely new C-nor-D-homo steroids, without the need of a classic steran steroid rearrangement or achiral linear reaction sequences.