15199-41-4Relevant articles and documents
Oxidation of alkenes by oxodiperoxomolybdenum: Trialkyl(aryl)phosphine oxide complexes
Kiraz, Christine I. Altinis,Mora, Luis,Jimenez, Leslie S.
, p. 92 - 96 (2007)
Catalytic amounts of short-chain (2-4 carbons) trialkylphosphine oxide ligands and MoO5 have been shown to efficiently convert di- and higher substituted alkenes to the corresponding epoxides using a biphasic system with either 30% hydrogen peroxide or 70% TBHP acting as the stoichiometric oxidant. Georg Thieme Verlag Stuttgart.
Dendritic phosphonates and the in situ assembly of polyperoxophosphotungstates: Synthesis and catalytic epoxidation of alkenes with hydrogen peroxide
Vasylyev, Maxym V.,Astruc, Didier,Neumann, Ronny
, p. 39 - 44 (2007/10/03)
First and second-generation rigid dendrimers based on polyphenylated tetrahedral adamantane cores with four or sixteen peripheral phosphonate moieties, PD1 and PD2, respectively, were synthesized and characterized. Further reaction of the dendritic phosphonates with tungstic acid in the presence of hydrogen peroxide led to the stepwise in situ formation of mono- and dinuclear phosphoperoxotungstates. These assemblies were effective catalysts for the epoxidation of alkenes in an aqueous acetonitrile solvent.
Permanganate Ion Oxidations. 19. Hexadecyltrimethylammonium Permanganate Oxidation of Cycloalkenes
Freeman, Fillmore,Kappos, John C.
, p. 2730 - 2734 (2007/10/02)
The kinetics of hexadecyltrimethylammonium permanganate (cetyltrimethylammonium permanganate, CTAP) oxidation of cycloalkenes in dichloromethane have been studied.The relative rates of oxidation versus 13C NMR chemical shifts, vertical ionization potentials, and strain energies are discussed.A comparison of the relative rate of permanganate ion oxidation with the relative rates of addition of other reagents to carbon-carbon double bonds suggests that it may act as a 1,3-dipole.