15205-62-6Relevant articles and documents
Expeditious synthesis of 'P'-protected macrocycles en route to lanthanide chelate metal complexes
Manning, H. Charles,Bai, Mingfeng,Anderson, Bernard M.,Lisiak, Rafal,Samuelson, Lynn E.,Bornhop, Darryl J.
, p. 4707 - 4710 (2005)
Phosphonic acid appended tetraazacyclododecane (cyclen)-based macrocycles are attractive metal-ion chelators for diagnostic imaging and therapeutic delivery. Here, we report a novel P-protected methodology that facilitates the rapid synthesis and purifica
Highly efficient asymmetric mannich reaction of dialkyl α-diazomethylphosphonates with N -carbamoyl imines catalyzed by chiral bronsted acids
Zhang, Hui,Wen, Xiaojing,Gan, Lihua,Peng, Yungui
supporting information; experimental part, p. 2126 - 2129 (2012/07/17)
An efficient method involving the first use of chiral phosphoric acids as catalysts in the asymmetric Mannich reaction of dialkyl diazomethylphosphonates and N-carbamoyl imines is developed. With only 0.1 mol % catalyst 1f, the reaction proceeded smoothly and produced the corresponding β-amino-α- diazophosphonate with up to 97% yield and >99% ee.
Syntheses und NMR-Spektren phosphororganischer Antioxidantien und verwandter Verbindungen
Koenig, T.,Habicher, W.D.,Haehner, U.,Pionteck, J.,Rueger, C.,Schwetlick, K.
, p. 333 - 349 (2007/10/02)
The syntheses of various aliphatic, aromatic, sterically hindered, and cyclic organophosphorus compounds (phosphorous acid esters, esters chlorides and ester amides, hydrogen phosphites, phosphinates and phosphates) are reported, and general procedures for preparation are given.The compounds synthesized were investigated by means of 31P-, 1H- and 13C-n.m.r. spectroscopy, and the chemical shifts measured are listed.