152171-09-0Relevant articles and documents
Asymmetric Organocatalytic Synthesis of Bisindoles – Scope and Derivatizations
Retich, Christina,Br?se, Stefan
, p. 60 - 77 (2018/01/17)
Starting from 3-vinylindoles and glyoxolate imines, we created a library of diverse 4,6-bis(1H-indole-3-yl)piperidine 2-carboxylates by using 10 mol-% of a chiral phosphoric acid. Utilising electron-withdrawing groups on the starting material during the r
Gold(I)-catalyzed dearomative rautenstrauch rearrangement: Enantioselective access to cyclopenta[ b ]indoles
Zi, Weiwei,Wu, Hongmiao,Toste, F. Dean
supporting information, p. 3225 - 3228 (2015/03/30)
A highly enantioselective dearomative Rautenstrauch rearrangement catalyzed by cationic (S)-DTBM-Segphosgold(I) is reported. This reaction provides a straightforward method to prepare enantioenriched cyclopenta[b]indoles. These studies show vast differenc