15228-38-3

Basic information

• Product Name: (acetonitrile)pentacarbonylchromium
• Synonyms: (acetonitrile)pentacarbonylchromium
• CAS NO: 15228-38-3
• Molecular Weight: 233.101
• Mol File: 15228-38-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (acetonitrile)pentacarbonylchromium(CAS DataBase Reference)
• NIST Chemistry Reference: (acetonitrile)pentacarbonylchromium(15228-38-3)
• EPA Substance Registry System: (acetonitrile)pentacarbonylchromium(15228-38-3)

Safety Data

• Hazardous Substances Data: 15228-38-3(Hazardous Substances Data)

Upstream product

• 22852-50-2 pentacarbonyl{amino(methyl)methylene}chromium 
• 100-52-7 benzaldehyde 

Downstream Products

• 106859-35-2 (2-p-tolylthio-4-methyl-1,3,2-dioxaphosphorinane)pentacarbonylchromium⁽⁰⁾ 
• 106859-34-1 (2-p-tolyloxy-4-methyl-1,3,2-dioxaphosphorinane)pentacarbonylchromium⁽⁰⁾ 
• 199620-14-9 chromium⁽⁰⁾ hexacarbonyl 
• 31172-86-8 (CO)5Cr*S(CH₃)Au(P(C₆H₅)3)=(CO)5CrS(CH₃)AuP(C₆H₅)3 
• 82742-75-4 (CO)5Cr(OP₂(C₆H₅)4) 
• 90590-24-2 Mo(CO)5P(C₆H₅)2OP(C₆H₅)2Cr(CO)5 
• 160954-47-2 1-phenylthio-3,4-dimethyl-3-arsolene pentacarbonylchromium 
• 160954-45-0 1-phenyl-3,4-dimethyl-3-arsolene pentacarbonylchromium 
• 148353-87-1 {μ-bis(diphenylphosphino)methane}-bis{pentacarbonylchromium(0)} 
• 15024-28-9 Cr2(CO)10(μ-1,2-bis(diphenylphosphino)ethane) 
• 127550-79-2 (CO)5Cr{Ph₂P(CH₂)4NCHC₆H₄-o-OH} 
• 127522-46-7 trans-(CO)4Cr{Ph₂P(CH₂)4NCHC₆H₄-o-OH}2 
• 31172-87-9 (CO)5CrSP(C₆H₅)2CH₃ 
• 113803-76-2 1,3-bis(diphenylphosphino)propanedichromium decacarbonyl 

Relevant articles and documents

Organic Syntheses via Transition Metal Complexes, 33. - 2-Azaallenyl Chromium Complexes by Condensation of Aminocarbene Chromium Complexes with Aldehydes, Acid Chlorides, or Acid Amides

Aminocarbene complexes LnM=C(NH2)R 1 can be converted to 2-azaallenyl complexes LnM-+=CXR1> by the condensation of the NH2 group with organic carbonyl compounds O=CYR1 in presence of Et3N and POCl3/Et3N, respectively.The condensation is achieved with a surprisingly wide variety of different carbonyl compounds like aldehydes (Y = H); acid chlorides (Y = Cl), acid amides and leads to the formation of 2-azaallenyl complexes of hitherto unknown substitution patterns 1 (7), N(CH3)2 (9)>.These have been analysed spectroscopically. 3a was characterized by an X-ray analysis. - Keywords: 2-Azaallenyl chromium complexes/ CNC building blocks/ Aminocarbene complexes