160954-45-0

Basic information

• Product Name: 1-phenyl-3,4-dimethyl-3-arsolene pentacarbonylchromium
• CAS NO: 160954-45-0
• Molecular Weight: 426.221
• Mol File: 160954-45-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-phenyl-3,4-dimethyl-3-arsolene pentacarbonylchromium(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenyl-3,4-dimethyl-3-arsolene pentacarbonylchromium(160954-45-0)
• EPA Substance Registry System: 1-phenyl-3,4-dimethyl-3-arsolene pentacarbonylchromium(160954-45-0)

Safety Data

• Hazardous Substances Data: 160954-45-0(Hazardous Substances Data)

Upstream product

• 15228-38-3 (acetonitrile)pentacarbonylchromium 
• 73411-22-0 1-phenyl-3,4-dimethyl-3-arsolene 

Relevant articles and documents

Reaktive Arsen-Heterocyclen. III. 3-Arsolene: Synthese und Reaktionen am Arsen

3-Arsolenes (R=Ph, Me, t-Bu, Cl, R'=H, Me) are readily obtained from zirconocene-butadiene complexes and RAsCl2.Alkylation with methyl iodide gives arsonium salts (R=Ph, Me, t-Bu, R'=H, Me), treatment with sulphur gives sulphides (R=Me, t-Bu), while oxidation with Br2 or SO2Cl2 results in ring cleavage.From chloroarsolene substitution products (R=I, H, SPh, OMe, NMe2) as well as coupling products with As-As, As-O-As, and As-S-As units were synthesized.In addition, a number of arsolene complexes with the metals chromium, molybdenum, tungsten, and ruthenium is described. Key words: Arsolene; Zirconocene; Group 6; Ruthenium; Phosphorus