152386-86-2Relevant articles and documents
A formal synthesis of 3-O-(4-methoxybenzyl)-azidosphingosine by a modified Julia olefination
Compostella, Federica,Franchini, Laura,Panza, Luigi,Prosperi, Davide,Ronchetti, Fiamma
, p. 4425 - 4428 (2007/10/03)
The stereoselective construction of the D-erythro-azidosphingosine characteristic trans double bond was accomplished by condensation between tetradecanal and a heterocyclic sulfone derived from diethyl-D-tartrate, following the Kocienski modification of the Julia olefination.
An enantiospecific synthesis of D-erythro-sphingosine from D-tartaric acid
Somfai, Peter,Olsson, Roger
, p. 6645 - 6650 (2007/10/02)
An efficient enantiospecific synthesis of D-erythro-sphingosine (1) via azidosphingosine (2) is described, the absolute stereochemistry being derived from D-tartaric acid.