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3-(3-AMINOPHENOXY)ANILINE, also known as 3,3'-Oxydianiline, is an organic compound with the molecular formula C12H11NO2. It is a derivative of aniline, featuring an amino group and a phenoxy group attached to the benzene ring. 3-(3-AMINOPHENOXY)ANILINE is known for its chemical reactivity and is commonly used as a building block in the synthesis of various organic compounds, particularly in the field of materials science.

15268-07-2

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15268-07-2 Usage

Uses

Used in the Chemical Industry:
3-(3-AMINOPHENOXY)ANILINE is used as a reactant for the synthesis of various organic compounds, particularly in the development of new materials with unique properties. Its presence in the molecular structure allows for the formation of different chemical bonds, which can lead to the creation of novel compounds with specific characteristics.
Used in the Pharmaceutical Industry:
3-(3-AMINOPHENOXY)ANILINE is used as an intermediate in the synthesis of pharmaceutical compounds, where its unique structure can contribute to the development of new drugs with improved efficacy and reduced side effects.
Used in the Electronics Industry:
3-(3-AMINOPHENOXY)ANILINE is used as a reactant in the synthesis of a deep blue electrophosphorescent Pt(II) emitter. This application takes advantage of the compound's ability to form stable complexes with metal ions, which can exhibit unique optical properties, making it suitable for use in the development of advanced electronic devices such as organic light-emitting diodes (OLEDs) and other optoelectronic applications.

Check Digit Verification of cas no

The CAS Registry Mumber 15268-07-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,5,2,6 and 8 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 15268-07:
(7*1)+(6*5)+(5*2)+(4*6)+(3*8)+(2*0)+(1*7)=102
102 % 10 = 2
So 15268-07-2 is a valid CAS Registry Number.
InChI:InChI=1/C12H12N2O/c13-9-3-1-5-11(7-9)15-12-6-2-4-10(14)8-12/h1-8H,13-14H2

15268-07-2Relevant academic research and scientific papers

INTRAMOLECULAR EXCHANGE COUPLING OF ARYLNITRENES BY OXYGEN

Minato, Masaki,Lahti, Paul M.

, p. 495 - 502 (1994)

A series of m,n'-diazidodiphenyl ethers (m -1, and also showed a weak dinitrene quintet spectrum with /D/hc/=0.162 cm-1 having ESR spectral intensity vs temperature dependence (Curie law) consistent with either a high-spin ground state or a very small singlet-quintet gap.Di(3-azidophenyl) ether gave a strong mononitrene peak with /D/hc/=0.996 cm-1 and a quintet dinitrene ESR spectrum (/D/hc/=0.162 cm-1) which exhibited non-linear Curie law intensity behavior consistent with the quintet being a thermally populated excited state 40 cal mol-1 above a singlet ground state.Di(4-azidophenyl) ether gave a strong mononitrene peak with /D/hc/=0.961 cm-1, but no observable spectrum related to a high-spin open-shell dinitrene.The results are consistent with oxygen being a weak exchange coupling linker in pi-conjugated open-shell molecules.The observed ground-state spin multiplicities are in accord with qualitative superexchange and connectivity models, despite any perturbations due to resonance effects between the oxygen linker and p-nitrene sites.

ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES

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Paragraph 0125, (2019/06/15)

A compound of Formula I is disclosed.

Organic electroluminescent materials and devices

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Page/Page column 195-196, (2016/10/27)

Novel phosphorescent platinum complexes containing tetradentate ligands are provided. The disclosed compounds have three 6-membered metallocycle units in each tertadentate ligand. The disclosed compounds have desirable electronic properties that make them useful when incorporated into a variety of OLED devices.

A common diaryl ether intermediate for the gram-scale synthesis of oxazine and xanthene fluorophores

Anzalone, Andrew V.,Wang, Tracy Y.,Chen, Zhixing,Cornish, Virginia W.

supporting information, p. 650 - 654 (2013/02/23)

Common ground: Copper-catalyzed coupling reactions can be used for the high-yielding preparation of widely used oxazine and xanthene fluorophores from a common diaryl ether intermediate on a gram-scale (see scheme). This general approach may facilitate th

Orthogonal Cu- and Pd-based catalyst systems for the O- and N-arylation of aminophenols

Maiti, Debabrata,Buchwald, Stephen L.

supporting information; experimental part, p. 17423 - 17429 (2010/03/25)

O- or N-arylated aminophenol products constitute a common structural motif in various potentially useful therapeutic agents and/or drug candidates. We have developed a complementary set of Cu- and Pd-based catalyst systems for the selective O- and N-arylation of unprotected aminophenols using aryl halides. Selective O-arylation of 3- and 4-aminophenols is achieved with copper-catalyzed methods employing picolinic acid or CyDMEDA, trans-N,N′-dimethyl-1,2- cyclohexanediamine, respectively, as the ligand. The selective formation of N-arylated products of 3- and 4-aminophenols can be obtained with BrettPhos precatalyst, a biarylmonophosphine-based palladium catalyst. 2-Aminophenol can be selectively N-arylated with CuI, although no system for the selective O-arylation could be found. Coupling partners with diverse electronic properties and a variety of functional groups can be selectively transformed under these conditions.

Synthesis and characterization of a new red-emitting Ca2+ indicator, calcium ruby

Gaillard, Stephane,Yakovlev, Aleksey,Luccardini, Camilla,Oheim, Martin,Feltz, Anne,Mallet, Jean-Maurice

, p. 2629 - 2632 (2008/02/10)

Equation Presented Calcium Ruby m-Cl (X = H, Y = Cl) is a visible-light excited red-emitting calcium concentration ([Ca2+]) indicator dye (579/598 nm peak excitation/emission) with a side arm for conjugation via EDC or click chemistry. Its larg

Effect of synthesis conditions on formation of partially crystalline polyimides based on meta-substituted binuclear diamines

Kudryavtsev,Meleshko,Kalbin,Bogorad,Lukasov,Baklagina

, p. 2171 - 2176 (2007/10/03)

Partially crystalline polyimides were prepared from 3,3′,4,4′-benzophenonetetracarboxylic acid and meta-substituted binuclear diamines. The products exhibit clearly pronounced softening and melting points, which are lower than the temperature of the onset of thermal degradation.

Thermoplastic resin composition and a method of molding the same

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, (2008/06/13)

This invention provides a thermoplastic resin composition comprising a thermoplastic resin and 0.1 to 100 parts by weight, per 100 parts by weight of the thermoplastic resin, of an imide compound prepared, e.g., by dehydration condensation of 1,2,3,4-butanetetracarboxylic acid or a monoanhydride or a dianhydride thereof with a primary amine, and a method of molding the resin composition.

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