1527482-54-7

Basic information

• Product Name: 1-isopropyl-3-((3E,7E)-4,8,10-trimethylundeca-3,7,9-trienyl)benzene
• Synonyms: 1-isopropyl-3-((3E,7E)-4,8,10-trimethylundeca-3,7,9-trienyl)benzene
• CAS NO: 1527482-54-7
• Molecular Weight: 310.523
• Mol File: 1527482-54-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-isopropyl-3-((3E,7E)-4,8,10-trimethylundeca-3,7,9-trienyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-isopropyl-3-((3E,7E)-4,8,10-trimethylundeca-3,7,9-trienyl)benzene(1527482-54-7)
• EPA Substance Registry System: 1-isopropyl-3-((3E,7E)-4,8,10-trimethylundeca-3,7,9-trienyl)benzene(1527482-54-7)

Safety Data

• Hazardous Substances Data: 1527482-54-7(Hazardous Substances Data)

Upstream product

• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 37905-02-5 (2E,6E)-3,7-dimethyl-8-oxoocta-2,6-dien-1-yl acetate 
• 1527482-52-5 (2E,6E)-3,7,9-trimethyldeca-2,6,8-trienyl acetate 
• 5433-01-2 1-bromo-3-isopropylbenzene 
• 51473-70-2 1-(m-isopropylphenyl)methanol 
• 37905-03-6 8-hydroxygeranyl acetate 

Downstream Products

• 1740-19-8 dehydroabietic acid 

Relevant articles and documents

Useful catalytic enantioselective cationic double annulation reactions initiated at an internal π-bond: Method and applications

The 1:1 complex of o,o'-dichloro-R-BINOL and SbCl5 initiates the enantioselective cationic polycyclization of polyunsaturated substrates at a predictable π-bond which may be either terminal or, as shown herein, internal. The extension of this powerful construction to internal π-bonds expands the scope of this method and opens up very short pathways to numerous chiral polycyclic molecules, including natural products and their analogues. Especially simple synthetic routes are disclosed that provide access to dysideapalaunic acid, dehydroabietic acid, and epipodocarpic acid and illustrate the value of this enantioselective approach.