5433-01-2

Basic information

• Product Name: 3-Bromocumene
• Synonyms: 3-BROMOISOPROPYLBENZENE;3-BROMOCUMENE;3-ISOPROPYLBROMOBENZENE;1-BROMO-3-ISOPROPYLBENZENE;1-Bromo-3-(1-methylethyl)benzene;Benzene,1-bromo-3-(1-methylethyl)-;cumene,3-bromo-;m-bromocumene
• CAS NO: 5433-01-2
• Molecular Formula: C₉H₁₁Br
• Molecular Weight: 199.09
• Mol File: 5433-01-2.mol
• Article Data: 8

Chemical Properties

• Melting Point: -10°C (estimate)
• Boiling Point: 52-53°C 0,8mm
• Flash Point: 52-53°C/0.8mm
• Appearance: /
• Density: 1,285 g/cm3
• Vapor Pressure: 0.277mmHg at 25°C
• Refractive Index: 1.5302
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility: Difficult to mix in water.
• BRN: 1858092
• CAS DataBase Reference: 3-Bromocumene(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Bromocumene(5433-01-2)
• EPA Substance Registry System: 3-Bromocumene(5433-01-2)

Safety Data

• Hazard Codes: Xi,N,Xn
• Statements: 22-50/53-51/53-36/38
• Safety Statements: 24/25-61-60-36-26
• RIDADR: 3082
• Hazardous Substances Data: 5433-01-2(Hazardous Substances Data)

Usage

Chemical Properties

Clear colorless to yellow liquid

Uses

It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs.

Synthesis Reference(s)

The Journal of Organic Chemistry, 25, p. 1691, 1960 DOI: 10.1021/jo01080a001

InChI:InChI=1/C9H11Br/c1-7(2)8-4-3-5-9(10)6-8/h3-7H,1-2H3

Upstream product

• 98-82-8 Isopropylbenzene 
• 3132-99-8 m-bromobenzoic aldehyde 
• 35739-70-9 dimethyldichlorotitanium(IV) 
• 51605-97-1 2-bromo-4-isopropylaniline 
• 12775-96-1 copper 
• 99-88-7 4-Isopropylaniline 
• 30951-66-7 2-(3-bromophenyl)-2-propanol 
• 25108-58-1 1-bromo-3-isopropenylbenzene 

Downstream Products

• 40751-59-5 3-isopropyl benzonitrile 
• 903583-57-3 2-bromo-3'-isopropyl-biphenyl 
• 216019-28-2 3-isopropylphenylboronic acid 
• 909416-48-4 1-cyclopentyl-3-(3-isopropyl-phenyl)-propan-1-one 
• 112930-12-8 α-(cumen-3'-yl)biphenyl-2-methanol 
• 59313-79-0 5-(3-isopropyl-phenyl)-3,7,3',7'-tetramethyl-5H-5λ⁵-[5,5']spirobi(benzo[b]phosphindole) 
• 5651-47-8 3-isopropylbenzoic acid 
• 99723-36-1 1-(3-isopropyl-phenyl)-ethanol 
• 5369-16-4 meta-iso-propyl aniline 
• 30951-66-7 2-(3-bromophenyl)-2-propanol 
• 41380-88-5 1-Cyclopropyl-3-isopropylbenzol 

Relevant articles and documents

ANTIHYPERTENSIVE POLYOL COMPOUND AND DERIVATIVE THEREOF

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Enantioselective copper-catalyzed conjugate addition of trimethylaluminium to β,γ-unsaturated α-ketoesters

Not a cop out: The copper-catalyzed asymmetric conjugate addition of organometallic reagents to Michael acceptors is an important methodology for forming a C-C bond in an enantioselective manner. Such an addition of Me 3Al to β,γ-unsaturated α-

Preparation of substituted bridged indenyl and related ligands

A process for preparing a chelating ligand of the formula (II) from a chelating ligand of the formula (I) via an sp2-sp2 or sp2-sp3 coupling reaction with an organometallic compound of the formula (III). wherein