15286-27-8Relevant academic research and scientific papers
Oxidative Phoshonylation of Aromatics with Ammonium Cerium(IV) Nitrate
Kottmann, Hariolf,Skarzewski, Jacek,Effenberger, Franz
, p. 797 - 801 (1987)
Arylphosphonates 5 and 6 can be prepared in good yields in a one-step synthesis starting from arenes with tri- or diethylphosphites and cerium ammonium nitrate (CAN) as oxidant.The seletivity of the oxidative phosphonylation is relatively low; the reactive species is a phosphite radical cation.
