Synthesis p. 797 - 801 (1987)
Update date:2022-07-30
Topics:
Kottmann, Hariolf
Skarzewski, Jacek
Effenberger, Franz
Arylphosphonates 5 and 6 can be prepared in good yields in a one-step synthesis starting from arenes with tri- or diethylphosphites and cerium ammonium nitrate (CAN) as oxidant.The seletivity of the oxidative phosphonylation is relatively low; the reactive species is a phosphite radical cation.
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