152860-22-5Relevant academic research and scientific papers
Tris(trimethylsilyl)silyl Radical Induced Bicyclization of 1,6-Dienes and 1,6-Enynes Providing 3,3-Bis(trimethylsilyl)-3-silabicyclooctanes and 3-Silabicyclooct-1-enes
Miura, Katsukiyo,Oshima, Koichiro,Utimoto, Kiitiro
, p. 2348 - 2355 (1993)
Treatment of 1,6-dienes with tris(trimethylsilyl)silane in the presence of Et3B or α,α'-azobis(isobutyronitrile) afforded 3,3-bis(trimethylsilyl)-3-silabicyclooctanes in addition to monocyclized cyclopentanes.Bicyclization of 1,6-enynes provided th
