
Bulletin of the Chemical Society of Japan p. 2348 - 2355 (1993)
Update date:2022-07-30
Topics:
Miura, Katsukiyo
Oshima, Koichiro
Utimoto, Kiitiro
Treatment of 1,6-dienes with tris(trimethylsilyl)silane in the presence of Et3B or α,α'-azobis(isobutyronitrile) afforded 3,3-bis(trimethylsilyl)-3-silabicyclo<3.3.0>octanes in addition to monocyclized cyclopentanes.Bicyclization of 1,6-enynes provided th
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