152985-29-0

Basic information

• Product Name: tert-butyl (S)-2-(1-phenylethyl)hydrazine-1-carboxylate
• Synonyms: tert-butyl (S)-2-(1-phenylethyl)hydrazine-1-carboxylate
• CAS NO: 152985-29-0
• Molecular Weight: 236.314
• Mol File: 152985-29-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: tert-butyl (S)-2-(1-phenylethyl)hydrazine-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl (S)-2-(1-phenylethyl)hydrazine-1-carboxylate(152985-29-0)
• EPA Substance Registry System: tert-butyl (S)-2-(1-phenylethyl)hydrazine-1-carboxylate(152985-29-0)

Safety Data

• Hazardous Substances Data: 152985-29-0(Hazardous Substances Data)

Upstream product

• 98-86-2 acetophenone 
• 2627-86-3 (S)-1-phenyl-ethylamine 
• 462100-44-3 oxaziridine-2,3,3-tricarboxylic acid 2-tert-butyl ester 3,3-diethyl ester 
• 56572-27-1 tert-butyl N'-(1-phenylethylidene)hydrazinecarboxylate 

Relevant articles and documents

Nickel-Catalyzed Asymmetric Hydrogenation of Hydrazones

An efficient nickel-catalyzed asymmetric hydrogenation of hydrazones to chiral hydrazines has been realized with up to 99 % yield and 99.4 : 0.6 er. Deuterium labelling experiments indicated that the hydrazone substrates undergo imine-enamine tautomerizat

Catalytic enantioselective hydrogenation of N-alkoxycarbonyl hydrazones: A practical synthesis of chiral hydrazines

(Figure presented) An enantioselective hydrogenation of hydrazones catalyzed by Rh complexes (Rh-Josiphos or Rh-Taniaphos) has been developed. The protocol can be applied to hydrazones with three different protective groups (Boc, Cbz, and methoxycarbonyl)